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However, the \u201cstress singularity\u201d effect arising from heterogeneous interfaces gradually leads to interfacial slippage and further triggers electrical isolation, fundamentally resulting in mechanical failure and kinetic heterogeneity within the electrode. Herein, we realize conformal interlocking between silicon oxycarbide (SiOC) and discrete graphite domains in developed omnidirectional conformal interface SiOC\u2013graphite (OSiOCG) electrodes to overcome the \u201cstress singularity\u201d effect. Mechanically, the omnidirectional conformal interface effectively transforms localized piercing force into hydrostatically distributed compressive force, effectively dissipating the \u201cstress singularity\u201d effect. Kinetically, it crosslinks isolated sites of transfer of electron\/Li\u2010ion into 3D\u2010percolation networks across the entire interface. This mitigates local polarization, regulates the sequence and depth of lithiation for active components, and further dissipates the concentrated stress. The OSiOCG electrodes deliver stabilized cycling for 2000 cycles (average capacity decay &lt; 0.005% per cycle), optimized rate capability (capacity increases of 19.3% at 4C and 12.8% at 10C), and effective practicality validated in pouch cells (88.3% capacity retention at 4C). This work sheds light on interfacial stress delocalization within Si\u2010based graphite composite electrodes while paving the way for long\u2010term reliability enhancement of commercialized high\u2010energy\u2010density LIBs.<\/jats:p>","DOI":"10.1002\/adma.74587","type":"journal-article","created":{"date-parts":[[2026,8,12]],"date-time":"2026-08-12T07:52:26Z","timestamp":1786521146000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":1,"title":["Coupling Stress Delocalization With Lithiation Homogenization: Omnidirectional Conformal Interface Integrating Silicon Oxycarbide\u2013Graphite Anode"],"prefix":"10.1002","volume":"38","author":[{"given":"Pingshan","family":"Jia","sequence":"first","affiliation":[{"name":"Institute of Applied Physics and Materials Engineering University of Macau  Taipa Macau 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