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Herein, we report a quasi\u2010solid hybrid electrolyte (HM) by integrating polyacrylamide with a rigid inorganic montmorillonite (MMT) framework that imposes strong \u00e5ngstr\u00f6m confinement on interlayer water molecules. Such spatial confinement restricts the volume required to assemble a bulk three\u2010dimensional tetrahedral hydrogen\u2010bond network. Concurrently, polar Si\u2010O bonds on the MMT surface chemically anchor water molecules in a one\u2010hydrogen\u2010down configuration, inducing symmetry breaking and topological frustration. Consequently, Grotthuss\u2010type proton transport and water autoionization are suppressed. This molecular\u2010level regulation mitigates water\u2010induced parasitic reactions and byproduct accumulation, ensuring a reversible Zn\/electrolyte interface. As a result, the assembled Zn||NH\n                    <jats:sub>4<\/jats:sub>\n                    V\n                    <jats:sub>4<\/jats:sub>\n                    O\n                    <jats:sub>10<\/jats:sub>\n                    full cell achieves stable cycling for over 800 cycles at 1\u00a0A\u00a0g\n                    <jats:sup>\u22121<\/jats:sup>\n                    . By shifting the electrolyte design toward \u00e5ngstr\u00f6m topological engineering, this work establishes a promising paradigm for suppressing water\u2010induced parasitic reactions in high\u2010performance AZIBs.\n                  <\/jats:p>","DOI":"10.1002\/adma.74640","type":"journal-article","created":{"date-parts":[[2026,8,14]],"date-time":"2026-08-14T06:35:59Z","timestamp":1786689359000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":2,"title":["Topological Frustration of \u00c5ngstr\u00f6m\u2010Confined Water for Stable Aqueous Zinc\u2010Ion Batteries"],"prefix":"10.1002","volume":"38","author":[{"given":"Yufeng","family":"Liao","sequence":"first","affiliation":[{"name":"School of Materials Science and Engineering Hunan Provincial Key Laboratory of Electronic Packaging and Advanced Functional Materials Central South University  Changsha Hunan People's Republic of 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