{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,16]],"date-time":"2026-10-16T15:58:13Z","timestamp":1792166293895,"version":"4.4.0"},"reference-count":60,"publisher":"Wiley","issue":"58","license":[{"start":{"date-parts":[[2026,8,17]],"date-time":"2026-08-17T00:00:00Z","timestamp":1786924800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,8,17]],"date-time":"2026-08-17T00:00:00Z","timestamp":1786924800000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100012166","name":"National Key Research and Development Program of China","doi-asserted-by":"publisher","award":["2024YFE0211700"],"award-info":[{"award-number":["2024YFE0211700"]}],"id":[{"id":"10.13039\/501100012166","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22374144"],"award-info":[{"award-number":["22374144"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["advanced.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Advanced Materials"],"published-print":{"date-parts":[[2026,10]]},"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    Circularly polarized electrochemiluminescence (CP\u2010ECL) provides an emerging route to encode chiral information into electrochemically generated light, but current strategies largely rely on intrinsically chiral luminophores, limiting molecular diversity, device integration, and dissymmetry\u2010factor amplification. Here, a strategy based on engineered chiroplasmonic nanointerfaces is developed for high\u2010dissymmetry CP\u2010ECL from achiral luminophores. In this design, luminophores are spatially confined around helicoid Au nanocrystals within a nanoscale plasmonic environment, and the resulting hybrid nanocrystals are assembled into monolayer films to couple chiroplasmonic near fields with electrochemically generated excited states. Using Ru(bpy)\n                    <jats:sub>3<\/jats:sub>\n                    <jats:sup>2+<\/jats:sup>\n                    as a model achiral ECL luminophore, the helicoid Au@SiO\n                    <jats:sub>2<\/jats:sub>\n                    \u2010Ru nanocrystal monolayer electrode produces mirror\u2010image CP\u2010ECL responses with a high dissymmetry factor of |g\n                    <jats:sub>CP\u2010ECL<\/jats:sub>\n                    |\u00a0\u2248\u00a01.1. Control experiments and electromagnetic simulations reveal a synergistic mechanism in which chiroplasmonic near\u2010field induction predominantly breaks the emission symmetry, whereas circular\u2010polarization\u2010dependent extinction further amplifies the far\u2010field circular polarization contrast. Extension to another achiral ECL luminophore suggests that this strategy may be applicable beyond the Ru(bpy)\n                    <jats:sub>3<\/jats:sub>\n                    <jats:sup>2+<\/jats:sup>\n                    system. By enabling circular polarization without requiring intrinsically chiral luminophores, this approach can be readily integrated with established achiral ECL chemistries and devices, offering opportunities for chiral sensing, electrochemiluminescent photonics, and optical information encoding.\n                  <\/jats:p>","DOI":"10.1002\/adma.74684","type":"journal-article","created":{"date-parts":[[2026,8,17]],"date-time":"2026-08-17T08:30:36Z","timestamp":1786955436000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Engineered Chiroplasmonic Nanointerfaces Enable High\u2010Dissymmetry Circularly Polarized Electrochemiluminescence From Achiral Luminophores"],"prefix":"10.1002","volume":"38","author":[{"given":"Wenping","family":"Gao","sequence":"first","affiliation":[{"name":"Key Laboratory of Electroanalytical Chemistry Changchun Institute of Applied Chemistry Chinese Academy of Sciences  Changchun 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