{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,16]],"date-time":"2026-10-16T16:43:39Z","timestamp":1792169019842,"version":"4.4.0"},"reference-count":57,"publisher":"Wiley","issue":"58","license":[{"start":{"date-parts":[[2026,8,19]],"date-time":"2026-08-19T00:00:00Z","timestamp":1787097600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,8,19]],"date-time":"2026-08-19T00:00:00Z","timestamp":1787097600000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["52373260"],"award-info":[{"award-number":["52373260"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["51921002"],"award-info":[{"award-number":["51921002"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["51927806"],"award-info":[{"award-number":["51927806"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["advanced.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Advanced Materials"],"published-print":{"date-parts":[[2026,10]]},"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    Enhanced demand for high\u2010energy\u2010density batteries has intensified the focus on high\u2010voltage Ni\u2010rich ternary cathodes. However, their high\u2010voltage characteristics are challenging to match the narrow electrochemical stability window of traditional ether electrolytes. Herein, we propose a series of unilateral\u2010cyano\u2010functionalized asymmetric glyme (glyme\u2010CN) electrolytes with broadened oxidation stability by molecular engineering. The electron\u2010withdrawing cyano group enhances oxidation stability by suppressing ether\u2010oxygen lone pair loss, while their solvation structures are finely tuned to promote anion\u2010derived interfacial chemistry. The optimized electrolyte glyme\u2010CN named TF achieves a 5.2\u00a0V electrochemical stability window, 98.9% Coulombic efficiency in Li||Cu cells, and stable cycling in Li||Li cells over 1400 h. The Li||LiFePO\n                    <jats:sub>4<\/jats:sub>\n                    full battery with electrolyte TF delivers remarkable cycling stability, maintaining 133.3 mAh g\n                    <jats:sup>\u22121<\/jats:sup>\n                    high capacity with a 90.8% capacity retention rate after 4000 cycles at 1C. Furthermore, TF enables a 4.3\u00a0V LiNi\n                    <jats:sub>0.8<\/jats:sub>\n                    Co\n                    <jats:sub>0.1<\/jats:sub>\n                    Mn\n                    <jats:sub>0.1<\/jats:sub>\n                    O\n                    <jats:sub>2<\/jats:sub>\n                    cathode to retain 64.2% capacity after 800 cycles and sustains stable operation even at 4.6\u00a0V. This precise molecular engineering strategy for structure and property customization provides new insights into the development of advanced battery materials.\n                  <\/jats:p>","DOI":"10.1002\/adma.74706","type":"journal-article","created":{"date-parts":[[2026,8,19]],"date-time":"2026-08-19T11:28:58Z","timestamp":1787138938000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Unilateral\u2010Cyano\u2010Functionalized Asymmetric Ether\u2010Based Electrolytes Enable Stable High\u2010Voltage Lithium Metal Batteries"],"prefix":"10.1002","volume":"38","author":[{"given":"Yinuo","family":"Yu","sequence":"first","affiliation":[{"name":"Institute for Advanced Materials and Technology University of Science and Technology Beijing  Beijing P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zichen","family":"Wang","sequence":"additional","affiliation":[{"name":"School of Materials Science and Engineering Peking University  Beijing P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yixian","family":"Xiao","sequence":"additional","affiliation":[{"name":"Institute for Advanced Materials and Technology University of Science and Technology Beijing  Beijing P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jiajun","family":"Chen","sequence":"additional","affiliation":[{"name":"School of Materials Science and Engineering Peking University  Beijing P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xinzhao","family":"Xia","sequence":"additional","affiliation":[{"name":"Institute for Advanced Materials and Technology University of Science and Technology Beijing  Beijing P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yunxiao","family":"Ren","sequence":"additional","affiliation":[{"name":"Institute for Advanced Materials and Technology University of Science and Technology Beijing  Beijing P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shengyu","family":"Qin","sequence":"additional","affiliation":[{"name":"School of Materials Science and Engineering Peking University  Beijing P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Wenting","family":"Xie","sequence":"additional","affiliation":[{"name":"Institute for Advanced Materials and Technology University of Science and Technology Beijing  Beijing P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Bo","family":"Yang","sequence":"additional","affiliation":[{"name":"Institute for Advanced Materials and Technology University of Science and Technology Beijing  Beijing P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0005-4023-3583","authenticated-orcid":false,"given":"Jiale","family":"Liu","sequence":"additional","affiliation":[{"name":"Institute for Advanced Materials and Technology University of Science and Technology Beijing  Beijing P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1994-8531","authenticated-orcid":false,"given":"Lanying","family":"Zhang","sequence":"additional","affiliation":[{"name":"School of Materials Science and Engineering Peking University  Beijing P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0005-9207-6225","authenticated-orcid":false,"given":"Wei","family":"Hu","sequence":"additional","affiliation":[{"name":"Institute for Advanced Materials and Technology University of Science and Technology Beijing  Beijing P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3773-6666","authenticated-orcid":false,"given":"Huai","family":"Yang","sequence":"additional","affiliation":[{"name":"School of Materials Science and Engineering Peking University  Beijing P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,8,19]]},"reference":[{"key":"e_1_2_7_2_1","doi-asserted-by":"publisher","DOI":"10.1126\/sciadv.aas9820"},{"key":"e_1_2_7_3_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.201903325"},{"key":"e_1_2_7_4_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41560\u2010021\u201000910\u2010w"},{"key":"e_1_2_7_5_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.9b11056"},{"key":"e_1_2_7_6_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202000375"},{"key":"e_1_2_7_7_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41560\u2010023\u201001339\u2010z"},{"key":"e_1_2_7_8_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41560\u2010018\u20100199\u20108"},{"key":"e_1_2_7_9_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsenergylett.9b00381"},{"key":"e_1_2_7_10_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41560\u2010019\u20100464\u20105"},{"key":"e_1_2_7_11_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ensm.2021.04.002"},{"key":"e_1_2_7_12_1","doi-asserted-by":"publisher","DOI":"10.1039\/D3TA05535C"},{"key":"e_1_2_7_13_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.nanoen.2024.110454"},{"key":"e_1_2_7_14_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jpowsour.2008.09.113"},{"key":"e_1_2_7_15_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41563\u2010023\u201001508\u20101"},{"key":"e_1_2_7_16_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202112138"},{"key":"e_1_2_7_17_1","doi-asserted-by":"publisher","DOI":"10.1002\/bte2.20220049"},{"key":"e_1_2_7_18_1","doi-asserted-by":"publisher","DOI":"10.1002\/cphc.201402175"},{"key":"e_1_2_7_19_1","doi-asserted-by":"publisher","DOI":"10.1002\/bte2.20230018"},{"key":"e_1_2_7_20_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.mtener.2025.102090"},{"key":"e_1_2_7_21_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202404109"},{"key":"e_1_2_7_22_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202212342"},{"key":"e_1_2_7_23_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemmater.0c01489"},{"key":"e_1_2_7_24_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010022\u201029199\u20103"},{"key":"e_1_2_7_25_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202202143"},{"key":"e_1_2_7_26_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsenergylett.2c01090"},{"key":"e_1_2_7_27_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202204036"},{"key":"e_1_2_7_28_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202302543"},{"key":"e_1_2_7_29_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.nanoen.2023.108639"},{"key":"e_1_2_7_30_1","doi-asserted-by":"publisher","DOI":"10.1039\/D4EE02989E"},{"key":"e_1_2_7_31_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202204768"},{"key":"e_1_2_7_32_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41560\u2010023\u201001282\u2010z"},{"key":"e_1_2_7_33_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202202529"},{"key":"e_1_2_7_34_1","doi-asserted-by":"publisher","DOI":"10.1149\/1.2096876"},{"key":"e_1_2_7_35_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202100046"},{"key":"e_1_2_7_36_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41557\u2010024\u201001689\u20105"},{"key":"e_1_2_7_37_1","doi-asserted-by":"publisher","DOI":"10.1002\/bte2.20230044"},{"key":"e_1_2_7_38_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.nanolett.5b05283"},{"key":"e_1_2_7_39_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202001440"},{"key":"e_1_2_7_40_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ensm.2023.102782"},{"key":"e_1_2_7_41_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.carbon.2021.02.075"},{"key":"e_1_2_7_42_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201807034"},{"key":"e_1_2_7_43_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.nanoen.2020.104860"},{"key":"e_1_2_7_44_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.1c04517"},{"key":"e_1_2_7_45_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jechem.2020.07.009"},{"key":"e_1_2_7_46_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202211364"},{"key":"e_1_2_7_47_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202108400"},{"key":"e_1_2_7_48_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202003752"},{"key":"e_1_2_7_49_1","doi-asserted-by":"publisher","DOI":"10.1002\/smll.202103375"},{"key":"e_1_2_7_50_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202212605"},{"key":"e_1_2_7_51_1","doi-asserted-by":"publisher","DOI":"10.1039\/C9TA09505E"},{"key":"e_1_2_7_52_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.3c07482"},{"key":"e_1_2_7_53_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcis.2022.08.018"},{"key":"e_1_2_7_54_1","doi-asserted-by":"publisher","DOI":"10.1149\/1.2133112"},{"key":"e_1_2_7_55_1","doi-asserted-by":"publisher","DOI":"10.1073\/pnas.2316212121"},{"key":"e_1_2_7_56_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsenergylett.4c00519"},{"key":"e_1_2_7_57_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.4c16561"},{"key":"e_1_2_7_58_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202315710"}],"container-title":["Advanced Materials"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/advanced.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/adma.74706","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/advanced.onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/adma.74706","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/advanced.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/adma.74706","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,10,16]],"date-time":"2026-10-16T15:43:39Z","timestamp":1792165419000},"score":1,"resource":{"primary":{"URL":"https:\/\/advanced.onlinelibrary.wiley.com\/doi\/10.1002\/adma.74706"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,8,19]]},"references-count":57,"journal-issue":{"issue":"58","published-print":{"date-parts":[[2026,10]]}},"alternative-id":["10.1002\/adma.74706"],"URL":"https:\/\/doi.org\/10.1002\/adma.74706","archive":["Portico"],"relation":{},"ISSN":["0935-9648","1521-4095"],"issn-type":[{"value":"0935-9648","type":"print"},{"value":"1521-4095","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,8,19]]},"assertion":[{"value":"2026-01-12","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-08-04","order":2,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-08-19","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e74706"}}