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The excessive swelling of flexible polymer networks, such as Nafion, often results in massive reactant crossover and diminished product yields. In this study, we report a swelling\u2010resistant membrane engineered from functionalized 1T\u2032 phase molybdenum disulfide (MoS\n                    <jats:sub>2<\/jats:sub>\n                    ). By covalently grafting acetamide groups onto the electron\u2010rich 1T\u2032\u2010MoS\n                    <jats:sub>2<\/jats:sub>\n                    , we create rigid nanochannels that physically exclude organic solvents while enabling efficient proton transport. This precise molecular sieving reduces organic permeability by an order of magnitude versus commercial Nafion 117, enabling near\u2010quantitative yields (&gt;96%) in diverse organic electrosynthesis reactions. Bridging the gap between lab and industrial application, we demonstrate scalable fabrication of this material via slot\u2010die coating, with the resulting large\u2010area membranes delivering robust stability and high productivity in a scaled\u2010up electrolyzer stack. These findings establish functionalized 2D channels as a general platform for designing next\u2010generation ion\u2010conductive membranes capable of operating in aggressive organic media.\n                  <\/jats:p>","DOI":"10.1002\/adma.74735","type":"journal-article","created":{"date-parts":[[2026,8,19]],"date-time":"2026-08-19T12:46:55Z","timestamp":1787143615000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Swelling\u2010Resistant Functionalized 1T\u2032\u2010MoS\n                    <sub>2<\/sub>\n                    Membranes for Crossover\u2010Free Organic Electrosynthesis"],"prefix":"10.1002","author":[{"given":"Qianqin","family":"Wang","sequence":"first","affiliation":[{"name":"New Cornerstone Science Laboratory State Key Laboratory for Physical Chemistry of Solid Surfaces and National &amp; Local Joint Engineering Research Center of Preparation Technology of Nanomaterials College of Chemistry and Chemical Engineering College of Energy Xiamen University  Xiamen P. 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