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However, the relentless pursuit of high performance is severely bottlenecked by intrinsic thermal safety concerns, where structural degradation and interfacial instability can trigger catastrophic thermal runaway. Herein, a thermally triggered domino effect, manifesting as a destructive chain reaction that initiates with severe interfacial side reactions at the cathode surface and sequentially propagates toward profound bulk structural collapse, is identified as the headstream of thermal failure. To mitigate these vulnerabilities, a scalable crystalline\u2010state composite strategy is proposed by integrating micrometer\u2010scale layered oxides with nanosized olivine\u2010structured oxides (LMFP). This rationally designed architecture also synergistically realizes volumetric compacted density up to 3.75\u00a0g cm\n                    <jats:sup>\u22123<\/jats:sup>\n                    and 86% capacity retention over 1000 cycles. Specifically, LMFP affords a dual\u2010spatial stabilization: it directs the formation of a robust inorganic\u2010rich cathode\u2013electrolyte interphase while simultaneously functioning as an internal thermal barrier to effectively interrupt this detrimental chain reaction, resulting in 61.3\u00b0C and 21.4\u00b0C thermal failure delay for both cathodes and ampere\u2010hour\u2010level cells, respectively, which creates more than 16\u00a0min for evacuation during thermal runaway. This work elucidates a previously overlooked surface\u2010to\u2010bulk failure mechanism and delineates a highly viable trajectory for designing intrinsically safe, highly stable cathode architectures.\n                  <\/jats:p>","DOI":"10.1002\/adma.74738","type":"journal-article","created":{"date-parts":[[2026,8,27]],"date-time":"2026-08-27T08:18:32Z","timestamp":1787818712000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Interrupting Surface\u2010to\u2010Bulk Domino Propagation: A Thermal Failure Mitigation Strategy for Layered Oxide Cathodes"],"prefix":"10.1002","author":[{"given":"Yulong","family":"Wang","sequence":"first","affiliation":[{"name":"Institute of Advanced Battery Materials and Devices College of New Energy Beijing University of Technology  Beijing China"},{"name":"Institute of Gongda\u2010Guochuang Advanced Battery Materials and Devices  Beijing China"},{"name":"College of Materials Science and Engineering State Key Laboratory of Materials Low\u2010Carbon Recycling Beijing University of Technology  Beijing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shiqi","family":"Liu","sequence":"additional","affiliation":[{"name":"Institute of Advanced Battery Materials and Devices College of New Energy Beijing University of Technology  Beijing China"},{"name":"Institute of Gongda\u2010Guochuang Advanced Battery Materials and Devices  Beijing China"},{"name":"College of Materials Science and Engineering State Key Laboratory of Materials Low\u2010Carbon Recycling Beijing University of Technology  Beijing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jingru","family":"Huang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Intelligent Green Vehicle and Mobility Tsinghua University  Beijing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Haozhe","family":"Du","sequence":"additional","affiliation":[{"name":"Institute of Advanced Battery Materials and Devices College of New Energy Beijing University of Technology  Beijing China"},{"name":"Institute of Gongda\u2010Guochuang Advanced Battery Materials and Devices  Beijing China"},{"name":"College of Materials Science and Engineering State Key Laboratory of Materials Low\u2010Carbon Recycling Beijing University of Technology  Beijing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Tian","family":"Wang","sequence":"additional","affiliation":[{"name":"Institute of Advanced Battery Materials and Devices College of New Energy Beijing University of Technology  Beijing China"},{"name":"Institute of Gongda\u2010Guochuang Advanced Battery Materials and Devices  Beijing China"},{"name":"College of Materials Science and Engineering State Key Laboratory of Materials Low\u2010Carbon Recycling Beijing University of Technology  Beijing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Fangzheng","family":"Liu","sequence":"additional","affiliation":[{"name":"Institute of Advanced Battery Materials and Devices College of New Energy Beijing University of Technology  Beijing China"},{"name":"Institute of Gongda\u2010Guochuang Advanced Battery Materials and Devices  Beijing China"},{"name":"College of Materials Science and Engineering State Key Laboratory of Materials Low\u2010Carbon Recycling Beijing University of Technology  Beijing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xianwei","family":"Guo","sequence":"additional","affiliation":[{"name":"Institute of Advanced Battery Materials and Devices College of New Energy Beijing University of Technology  Beijing China"},{"name":"Institute of Gongda\u2010Guochuang Advanced Battery Materials and Devices  Beijing China"},{"name":"College of Materials Science and Engineering State Key Laboratory of Materials Low\u2010Carbon Recycling Beijing University of Technology  Beijing China"},{"name":"Beijing Create Energy &amp; Benefit Future Co., Ltd.  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