{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,16]],"date-time":"2026-10-16T15:58:33Z","timestamp":1792166313346,"version":"4.4.0"},"reference-count":43,"publisher":"Wiley","issue":"58","license":[{"start":{"date-parts":[[2026,8,21]],"date-time":"2026-08-21T00:00:00Z","timestamp":1787270400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,8,21]],"date-time":"2026-08-21T00:00:00Z","timestamp":1787270400000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100012166","name":"National Key Research and Development Program of China","doi-asserted-by":"publisher","award":["2024YFE0217100"],"award-info":[{"award-number":["2024YFE0217100"]}],"id":[{"id":"10.13039\/501100012166","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["T2525023"],"award-info":[{"award-number":["T2525023"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["U23A20359"],"award-info":[{"award-number":["U23A20359"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["U25A6021"],"award-info":[{"award-number":["U25A6021"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100010428","name":"Innovation and Technology Fund","doi-asserted-by":"publisher","award":["GHP\/245\/22SZ"],"award-info":[{"award-number":["GHP\/245\/22SZ"]}],"id":[{"id":"10.13039\/501100010428","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["advanced.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Advanced Materials"],"published-print":{"date-parts":[[2026,10]]},"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    Organic\u2010inorganic hybrid materials glasses are increasingly recognized as a distinctive class within the broader field of glass science, because they extend the concept of glass formation from rigid atomic or polymeric networks to chemically programmable hybrid solids that integrate organic and inorganic building units. This emerging class of materials offers unusual opportunities for tuning optical, electronic, and structural properties, but its development is fundamentally limited by poor resistance to crystallization and devitrification. Here we report an A\u2010site cation engineering strategy to develop crystallization\u2010resistant zero\u2010dimensional antimony halide hybrid scintillator glasses. Replacing an allyl\u2010substituted triphenylphosphonium cation with a more conformationally flexible methoxymethyl analogue frustrates ordered packing, weakens directional intermolecular locking, and increases melt viscosity, thereby shifting the competition between crystallization and vitrification toward a persistent glassy state. The resulting transparent (MTPP)\n                    <jats:sub>2<\/jats:sub>\n                    SbCl\n                    <jats:sub>5<\/jats:sub>\n                    glass exhibits markedly enhanced resistance to thermally induced devitrification, together with efficient and stable luminescence and good irradiation tolerance. It enables centimeter\u2010scale scintillating monoliths for X\u2010ray imaging with a spatial resolution of 19.0\u00a0lp\u00a0mm\n                    <jats:sup>\u22121<\/jats:sup>\n                    at an MTF of 0.2, and can be further processed into active fibers for proof\u2010of\u2010concept remote X\u2010ray imaging.\n                  <\/jats:p>","DOI":"10.1002\/adma.74751","type":"journal-article","created":{"date-parts":[[2026,8,22]],"date-time":"2026-08-22T06:00:08Z","timestamp":1787378408000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Crystallization\u2010Resistant Hybrid Scintillator Glass for High\u2010Resolution and Remote X\u2010Ray Imaging"],"prefix":"10.1002","volume":"38","author":[{"ORCID":"https:\/\/orcid.org\/0009-0001-0758-1077","authenticated-orcid":false,"given":"Jiafu","family":"Yu","sequence":"first","affiliation":[{"name":"Engineering Research Center of Nano\u2010Geomaterials of Ministry of Education Faculty of Material Science and Chemistry China University of Geosciences  Wuhan China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0002-3346-316X","authenticated-orcid":false,"given":"Tingchang","family":"Shi","sequence":"additional","affiliation":[{"name":"Engineering Research Center of Nano\u2010Geomaterials of Ministry of Education Faculty of Material Science and Chemistry China University of Geosciences  Wuhan China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xinyi","family":"Li","sequence":"additional","affiliation":[{"name":"Engineering Research Center of Nano\u2010Geomaterials of Ministry of Education Faculty of Material Science and Chemistry China University of Geosciences  Wuhan China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yinghao","family":"Fan","sequence":"additional","affiliation":[{"name":"Engineering Research Center of Nano\u2010Geomaterials of Ministry of Education Faculty of Material Science and Chemistry China University of Geosciences  Wuhan China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiaojing","family":"Zhang","sequence":"additional","affiliation":[{"name":"Engineering Research Center of Nano\u2010Geomaterials of Ministry of Education Faculty of Material Science and Chemistry China University of Geosciences  Wuhan China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0003-3625-6825","authenticated-orcid":false,"given":"Ziming","family":"Song","sequence":"additional","affiliation":[{"name":"Engineering Research Center of Nano\u2010Geomaterials of Ministry of Education Faculty of Material Science and Chemistry China University of Geosciences  Wuhan China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0006-7784-9792","authenticated-orcid":false,"given":"Song","family":"He","sequence":"additional","affiliation":[{"name":"Research Institute of Huazhong University of Science and Technology  Shenzhen China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0163-4702","authenticated-orcid":false,"given":"Yue","family":"Hu","sequence":"additional","affiliation":[{"name":"School of Chemistry University of Edinburgh King's Buildings  Edinburgh UK"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4316-6807","authenticated-orcid":false,"given":"Yuting","family":"Gao","sequence":"additional","affiliation":[{"name":"Engineering Research Center of Nano\u2010Geomaterials of Ministry of Education Faculty of Material Science and Chemistry China University of Geosciences  Wuhan China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9285-4147","authenticated-orcid":false,"given":"Guangda","family":"Niu","sequence":"additional","affiliation":[{"name":"Research Institute of Huazhong University of Science and Technology  Shenzhen China"},{"name":"Wuhan National Laboratory For Optoelectronics Huazhong University of Science and Technology  Wuhan China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,8,21]]},"reference":[{"key":"e_1_2_8_2_1","doi-asserted-by":"publisher","DOI":"10.2138\/rmg.2022.87.23"},{"key":"e_1_2_8_3_1","doi-asserted-by":"publisher","DOI":"10.3390\/ma14112926"},{"key":"e_1_2_8_4_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202424218"},{"key":"e_1_2_8_5_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41578\u2010018\u20100054\u20103"},{"key":"e_1_2_8_6_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.aaz0251"},{"key":"e_1_2_8_7_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41557\u2010024\u201001616\u20108"},{"key":"e_1_2_8_8_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202302406"},{"key":"e_1_2_8_9_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202518282"},{"key":"e_1_2_8_10_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5c18721"},{"key":"e_1_2_8_11_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.matt.2024.04.004"},{"key":"e_1_2_8_12_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010024\u201049886\u20107"},{"key":"e_1_2_8_13_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202415483"},{"key":"e_1_2_8_14_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41578\u2010024\u201000759\u2010x"},{"key":"e_1_2_8_15_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202500925"},{"key":"e_1_2_8_16_1","doi-asserted-by":"publisher","DOI":"10.1002\/adom.202502024"},{"key":"e_1_2_8_17_1","doi-asserted-by":"publisher","DOI":"10.1002\/lpor.202301249"},{"key":"e_1_2_8_18_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsenergylett.6c00958"},{"key":"e_1_2_8_19_1","doi-asserted-by":"publisher","DOI":"10.1002\/adom.202300216"},{"key":"e_1_2_8_20_1","doi-asserted-by":"publisher","DOI":"10.1126\/sciadv.adu1982"},{"key":"e_1_2_8_21_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsnano.4c01761"},{"key":"e_1_2_8_22_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202416861"},{"key":"e_1_2_8_23_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010025\u201061416\u20107"},{"key":"e_1_2_8_24_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010026\u201068563\u20105"},{"key":"e_1_2_8_25_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41565\u2010024\u201001766\u20103"},{"key":"e_1_2_8_26_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.5c00425"},{"key":"e_1_2_8_27_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.4c04873"},{"key":"e_1_2_8_28_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010025\u201061410\u2010z"},{"key":"e_1_2_8_29_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202305942"},{"key":"e_1_2_8_30_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5c12026"},{"key":"e_1_2_8_31_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.4c07411"},{"key":"e_1_2_8_32_1","doi-asserted-by":"publisher","DOI":"10.1039\/D4MH01427H"},{"key":"e_1_2_8_33_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010025\u201061503\u20109"},{"key":"e_1_2_8_34_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemmater.5c01893"},{"key":"e_1_2_8_35_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.3c13156"},{"key":"e_1_2_8_36_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010025\u201062143\u20109"},{"key":"e_1_2_8_37_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.4c00768"},{"key":"e_1_2_8_38_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202503523"},{"key":"e_1_2_8_39_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.76100"},{"key":"e_1_2_8_40_1","doi-asserted-by":"publisher","DOI":"10.1002\/ange.202216504"},{"key":"e_1_2_8_41_1","doi-asserted-by":"publisher","DOI":"10.1039\/D3CC03752E"},{"key":"e_1_2_8_42_1","doi-asserted-by":"publisher","DOI":"10.1002\/adom.202301072"},{"key":"e_1_2_8_43_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202302140"},{"key":"e_1_2_8_44_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.nanolett.5c03109"}],"container-title":["Advanced Materials"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/advanced.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/adma.74751","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/advanced.onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/adma.74751","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/advanced.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/adma.74751","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,10,16]],"date-time":"2026-10-16T15:43:28Z","timestamp":1792165408000},"score":1,"resource":{"primary":{"URL":"https:\/\/advanced.onlinelibrary.wiley.com\/doi\/10.1002\/adma.74751"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,8,21]]},"references-count":43,"journal-issue":{"issue":"58","published-print":{"date-parts":[[2026,10]]}},"alternative-id":["10.1002\/adma.74751"],"URL":"https:\/\/doi.org\/10.1002\/adma.74751","archive":["Portico"],"relation":{},"ISSN":["0935-9648","1521-4095"],"issn-type":[{"value":"0935-9648","type":"print"},{"value":"1521-4095","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,8,21]]},"assertion":[{"value":"2026-04-14","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-08-14","order":2,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-08-21","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e74751"}}