{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,19]],"date-time":"2026-09-19T02:48:03Z","timestamp":1789786083593,"version":"4.0.1"},"reference-count":47,"publisher":"Wiley","license":[{"start":{"date-parts":[[2026,8,22]],"date-time":"2026-08-22T00:00:00Z","timestamp":1787356800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"},{"start":{"date-parts":[[2026,8,22]],"date-time":"2026-08-22T00:00:00Z","timestamp":1787356800000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/100000015","name":"U.S. Department of Energy","doi-asserted-by":"publisher","id":[{"id":"10.13039\/100000015","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100000001","name":"National Science Foundation","doi-asserted-by":"publisher","award":["NSF\u20102243895"],"award-info":[{"award-number":["NSF\u20102243895"]}],"id":[{"id":"10.13039\/100000001","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100000002","name":"National Institutes of Health","doi-asserted-by":"publisher","award":["S10OD036347"],"award-info":[{"award-number":["S10OD036347"]}],"id":[{"id":"10.13039\/100000002","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["advanced.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Advanced Materials"],"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    Mechanical recycling of mixed post\u2010consumer apolar\/polar polymers, due to their mis\u2010matched polarity and inherent immiscibility, is typically a downcycling process yielding brittle materials. An emerging method that can enhance recycling of such mixtures into dynamically crosslinked, high\u2010performance thermosets is a dynamic crosslinker (DC) platform; however, current DCs typically require an external catalyst and, due to their insufficiently high peak activation temperature (\n                    <jats:italic>T<\/jats:italic>\n                    <jats:sub>a<\/jats:sub>\n                    &lt;190\u00b0C), are limited to a subset of applicable polymers and unsuitable for industrial melt\u2010extrusion processing of high melting temperature (\n                    <jats:italic>T<\/jats:italic>\n                    <jats:sub>m<\/jats:sub>\n                    ) polymers. Herein, we report a trifunctional DC incorporating three sought\u2010after properties: thermally robust pyridotriazole cores as the high\u2010\n                    <jats:italic>T<\/jats:italic>\n                    <jats:sub>a<\/jats:sub>\n                    (245\u00b0C) crosslinking sites compatible with reactive extrusion up to 270\u00b0C; dynamic siloxane linkages as the robust yet exchangeable bonds; and pyridine\/ester functionalities as the internal catalysis sites devoid of external catalysts. Overall, this self\u2010catalyzed, high\u2010\n                    <jats:italic>T<\/jats:italic>\n                    <jats:sub>a<\/jats:sub>\n                    DC can compatibilize waste plastic mixtures containing high\n                    <jats:italic>T<\/jats:italic>\n                    <jats:sub>m<\/jats:sub>\n                    polymers and impart the recycled mixtures with superior thermoset properties such as enhanced creep resistance and thermomechanical stability while being melt\u2010(re)processable.\n                  <\/jats:p>","DOI":"10.1002\/adma.74752","type":"journal-article","created":{"date-parts":[[2026,8,22]],"date-time":"2026-08-22T16:16:32Z","timestamp":1787415392000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":1,"title":["Enhanced Mechanical Recycling of Polymer Mixtures by a Trifunctional Dynamic Crosslinker"],"prefix":"10.1002","author":[{"ORCID":"https:\/\/orcid.org\/0009-0005-2598-8339","authenticated-orcid":false,"given":"Xavier","family":"Westworth","sequence":"first","affiliation":[{"name":"Department of Chemistry Colorado State University  Fort Collins Colorado USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0000-3015-2169","authenticated-orcid":false,"given":"Essa","family":"Shamsan","sequence":"additional","affiliation":[{"name":"Department of Chemistry Colorado State University  Fort Collins Colorado USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2471-2427","authenticated-orcid":false,"given":"Yunpeng","family":"Gao","sequence":"additional","affiliation":[{"name":"Department of Chemistry Colorado State University  Fort Collins Colorado USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0000-9067-0697","authenticated-orcid":false,"given":"Nevaya","family":"Carr","sequence":"additional","affiliation":[{"name":"Department of Chemistry Colorado State University  Fort Collins Colorado USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7512-3484","authenticated-orcid":false,"given":"Eugene Y.\u2010X.","family":"Chen","sequence":"additional","affiliation":[{"name":"Department of Chemistry Colorado State University  Fort Collins Colorado USA"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,8,22]]},"reference":[{"key":"e_1_2_10_2_1","doi-asserted-by":"publisher","DOI":"10.1126\/sciadv.1700782"},{"key":"e_1_2_10_3_1","doi-asserted-by":"publisher","DOI":"10.3390\/ma14174782"},{"key":"e_1_2_10_4_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0GC02630A"},{"key":"e_1_2_10_5_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.clema.2024.100220"},{"key":"e_1_2_10_6_1","doi-asserted-by":"publisher","DOI":"10.1021\/acssuschemeng.8b02355"},{"key":"e_1_2_10_7_1","volume-title":"Global Plastics Outlook: Policy Scenarios to 2060","author":"OECD","year":"2022"},{"key":"e_1_2_10_8_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ese.2023.100256"},{"key":"e_1_2_10_9_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.watres.2019.04.060"},{"key":"e_1_2_10_10_1","doi-asserted-by":"publisher","DOI":"10.1039\/C5EM00207A"},{"key":"e_1_2_10_11_1","doi-asserted-by":"publisher","DOI":"10.1038\/s43247\u2010025\u201002169\u20105"},{"key":"e_1_2_10_12_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.wasman.2017.07.044"},{"key":"e_1_2_10_13_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41586\u2010021\u201004350\u20100"},{"key":"e_1_2_10_14_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.aaq0324"},{"key":"e_1_2_10_15_1","doi-asserted-by":"publisher","DOI":"10.1002\/marc.202000415"},{"key":"e_1_2_10_16_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscentsci.0c00567"},{"key":"e_1_2_10_17_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacsau.1c00500"},{"key":"e_1_2_10_18_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.macromol.8b01907"},{"key":"e_1_2_10_19_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsmacrolett.0c00339"},{"key":"e_1_2_10_20_1","volume-title":"Principles of Polymer Chemistry","author":"Flory P. J.","year":"1942"},{"key":"e_1_2_10_21_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.aah5744"},{"key":"e_1_2_10_22_1","doi-asserted-by":"publisher","DOI":"10.1073\/pnas.2301352120"},{"key":"e_1_2_10_23_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsapm.4c02270"},{"key":"e_1_2_10_24_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsami.9b20242"},{"key":"e_1_2_10_25_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsmacrolett.2c00601"},{"key":"e_1_2_10_26_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.4c05828"},{"key":"e_1_2_10_27_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5c06330"},{"key":"e_1_2_10_28_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsapm.4c04096"},{"key":"e_1_2_10_29_1","doi-asserted-by":"crossref","DOI":"10.1002\/pat.70183","article-title":"Industrially Adaptable Way for Upcycling of Mixed iPP and PE via In Situ Compatibilization","volume":"36","author":"Gao S.","year":"2025","journal-title":"Polymers for Advanced Technologies"},{"key":"e_1_2_10_30_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.3c12303"},{"key":"e_1_2_10_31_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5c20451"},{"key":"e_1_2_10_32_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5c20245"},{"key":"e_1_2_10_33_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41893\u2010025\u201001688\u20105"},{"key":"e_1_2_10_34_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202406203"},{"key":"e_1_2_10_35_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41586\u2010023\u201005858\u20103"},{"key":"e_1_2_10_36_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chempr.2025.102479"},{"key":"e_1_2_10_37_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.oprd.9b00422"},{"key":"e_1_2_10_38_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cclet.2024.110434"},{"key":"e_1_2_10_39_1","doi-asserted-by":"publisher","DOI":"10.1002\/ajoc.202200631"},{"key":"e_1_2_10_40_1","doi-asserted-by":"publisher","DOI":"10.1039\/C9SC02448D"},{"key":"e_1_2_10_41_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202303280"},{"key":"e_1_2_10_42_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.2c03518"},{"key":"e_1_2_10_43_1","doi-asserted-by":"publisher","DOI":"10.1039\/D4SC06278G"},{"key":"e_1_2_10_44_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202507313"},{"key":"e_1_2_10_45_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41570\u2010025\u201000686\u20107"},{"key":"e_1_2_10_46_1","doi-asserted-by":"publisher","DOI":"10.1039\/D4PY01355G"},{"key":"e_1_2_10_47_1","doi-asserted-by":"publisher","DOI":"10.1039\/D4SU00571F"},{"key":"e_1_2_10_48_1","doi-asserted-by":"publisher","DOI":"10.15255\/KUI.2022.072"}],"container-title":["Advanced Materials"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/advanced.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/adma.74752","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/advanced.onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/adma.74752","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/advanced.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/adma.74752","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,8,22]],"date-time":"2026-08-22T16:16:34Z","timestamp":1787415394000},"score":1,"resource":{"primary":{"URL":"https:\/\/advanced.onlinelibrary.wiley.com\/doi\/10.1002\/adma.74752"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,8,22]]},"references-count":47,"alternative-id":["10.1002\/adma.74752"],"URL":"https:\/\/doi.org\/10.1002\/adma.74752","archive":["Portico"],"relation":{},"ISSN":["0935-9648","1521-4095"],"issn-type":[{"value":"0935-9648","type":"print"},{"value":"1521-4095","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,8,22]]},"assertion":[{"value":"2026-05-01","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-08-14","order":2,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-08-22","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e74752"}}