{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,16]],"date-time":"2026-10-16T15:58:28Z","timestamp":1792166308190,"version":"4.4.0"},"reference-count":54,"publisher":"Wiley","issue":"58","license":[{"start":{"date-parts":[[2026,8,21]],"date-time":"2026-08-21T00:00:00Z","timestamp":1787270400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,8,21]],"date-time":"2026-08-21T00:00:00Z","timestamp":1787270400000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["52473213"],"award-info":[{"award-number":["52473213"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["advanced.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Advanced Materials"],"published-print":{"date-parts":[[2026,10]]},"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    Nonuniform Zn\n                    <jats:sup>2+<\/jats:sup>\n                    flux, which triggers dendritic growth and accompanying side reactions, severely bottlenecks the practical implementation of aqueous zinc\u2010ion batteries. While the interfacial electric field governs Zn\n                    <jats:sup>2+<\/jats:sup>\n                    flux uniformity, existing modulation strategies rely on static unidirectional fields remains intrinsically decoupled from the bidirectional, field\u2010reversing dynamics of cyclic Zn deposition\/stripping. Herein, we engineer a dynamic dipole\u2010flipping interlayer (DDL) on Zn anode that generates a switchable molecular\u2010level electric field to enable uniform Zn\n                    <jats:sup>2+<\/jats:sup>\n                    flux regulation during cycling. Specifically, the DDL is constructed from a rationally designed polyamide derivative featuring inherently large amide dipole moments; increased free volume and chain flexibility disrupt dense chain packing and enable rapid, reversible dipole reorientation. During Zn deposition\/stripping, the amide dipoles reorient dynamically to generate polarity\u2010switchable interfacial molecular\u2011level electric fields, which direct homogeneous Zn\n                    <jats:sup>2+<\/jats:sup>\n                    redistribution and suppress preferential nucleation. Beyond electric\u2011field regulation, fluorinated segments within the DDL impart interfacial hydrophobicity and further suppress side reactions. Consequently, the DDL\u2010modified Zn anode cycles stably for over 3200\u00a0h at 0.5\u00a0mA cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    , while the Zn||MnO\n                    <jats:sub>2<\/jats:sub>\n                    full cell delivers 97.3% capacity retention after 1600 cycles at 1\u00a0A g\n                    <jats:sup>\u22121<\/jats:sup>\n                    . This work pioneers a versatile paradigm for interfacial electric field regulation by dipole dynamics toward high\u2010performance aqueous metal\u2010based batteries.\n                  <\/jats:p>","DOI":"10.1002\/adma.74759","type":"journal-article","created":{"date-parts":[[2026,8,21]],"date-time":"2026-08-21T08:09:12Z","timestamp":1787299752000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":1,"title":["Dynamic Dipole\u2010Flipping Interlayer: Switchable Molecular\u2010Level Electric Field Enables Full\u2010Cycle Stable Zinc Anodes"],"prefix":"10.1002","volume":"38","author":[{"given":"Zhuanyi","family":"Liu","sequence":"first","affiliation":[{"name":"Key Laboratory of Synthetic and Biological Colloids Ministry of Education School of Chemical and Material Engineering Jiangnan University  Wuxi P. R. 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