{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,16]],"date-time":"2026-10-16T15:58:39Z","timestamp":1792166319501,"version":"4.4.0"},"reference-count":31,"publisher":"Wiley","issue":"58","license":[{"start":{"date-parts":[[2026,8,21]],"date-time":"2026-08-21T00:00:00Z","timestamp":1787270400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,8,21]],"date-time":"2026-08-21T00:00:00Z","timestamp":1787270400000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22279070"],"award-info":[{"award-number":["22279070"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100004826","name":"Natural Science Foundation of Beijing Municipality","doi-asserted-by":"publisher","award":["L242005"],"award-info":[{"award-number":["L242005"]}],"id":[{"id":"10.13039\/501100004826","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100012166","name":"National Key Research and Development Program of China","doi-asserted-by":"publisher","award":["2025YFF0513401"],"award-info":[{"award-number":["2025YFF0513401"]}],"id":[{"id":"10.13039\/501100012166","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["advanced.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Advanced Materials"],"published-print":{"date-parts":[[2026,10]]},"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    Pushing LiCoO\n                    <jats:sub>2<\/jats:sub>\n                    to \u22654.5\u00a0V causes coupled degradation: electrolyte oxidation and cathode structural collapse, especially at high rates. Here, we propose a triphase synergistic gel\u2010electrolyte to tackle both failure modes. The system, constructed by in situ thermal polymerization, integrates an ether\u2010rich crosslinked polymer network, surface\u2010activated AlN fillers with Lewis acid\u2013base sites, and a fluorinated electrolyte. This design regulates Li\n                    <jats:sup>+<\/jats:sup>\n                    transport, confines free solvent molecules, and reconstructs the solvation sheath. More importantly, it induces a uniform, inorganic\u2010rich cathode\u2013electrolyte interphase at an early stage. Consequently, LiCoO\n                    <jats:sub>2<\/jats:sub>\n                    \u2010based quasi\u2010solid\u2010state cells deliver exceptional stability: over 1000 cycles at 4.6\u00a0V and 5\u00a0C with an average decay of only \u223c0.03% per cycle, and 85.98% capacity retention after 500 cycles in practical Si\u2013C||LiCoO\n                    <jats:sub>2<\/jats:sub>\n                    pouch cells. Operando EIS\u2010DRT analysis reveals that the triphase electrolyte substantially suppresses the growth and fluctuation of interphase\u2010related polarization at high voltage, making the remaining impedance evolution more governed by transport\/contact processes. This work demonstrates that decoupling interfacial and structural degradation through a synergistic electrolyte design is key to realizing high\u2010voltage, high\u2010power, long\u2010life quasi\u2010solid\u2010state batteries.\n                  <\/jats:p>","DOI":"10.1002\/adma.74770","type":"journal-article","created":{"date-parts":[[2026,8,21]],"date-time":"2026-08-21T11:19:47Z","timestamp":1787311187000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["A Synergistic Triphase Electrolyte Design Enables 4.6\u00a0V LiCoO\n                    <sub>2<\/sub>\n                    Quasi\u2010Solid\u2010State Batteries with Ultra\u2010Long Cycling"],"prefix":"10.1002","volume":"38","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-8911-9267","authenticated-orcid":false,"given":"Sida","family":"Huo","sequence":"first","affiliation":[{"name":"School of Materials Science and Engineering University of Science and 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