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This imbalance promotes rapid C\u2500C condensation, and thereby limits aromatic monomers formation. Herein, a lignosulfonate\u2010derived RuO\n                    <jats:sub>2<\/jats:sub>\n                    \/ZnO carbon aerogel is constructed to synchronize C\u2500O bond activation by Lewis acid sites with ethanol\u2010mediated hydrogen transfer depolymerization of enzymatic hydrolysis lignin under N\n                    <jats:sub>2<\/jats:sub>\n                    . A metal\u2010directed gelation calcination route that organized Ru and Zn species within a polyacrylamide\u2010lignosulfonate network. This process yields a hierarchically porous, N\u2010doped carbon framework with closely connected and electronically coupled RuO\n                    <jats:sub>2<\/jats:sub>\n                    \/ZnO domains, this architecture creates a coupled catalytic microenvironment. Zn\u2010containing Lewis acidic sites polarize oxygenated linkages, whereas Ru sites activate ethanol to deliver transferable hydrogen species. ZnCl\n                    <jats:sub>2<\/jats:sub>\n                    serves as a mobile Lewis acid cocatalyst to further promote aryl ether and\n                    <jats:italic>\u03b2\u2013<\/jats:italic>\n                    O\u20134 activation. Under optimized conditions, phenol, guaiacol, and syringol type monomers are produced without external H\n                    <jats:sub>2<\/jats:sub>\n                    , increasing the aromatic monomer yield from 16.5% to 21.2%. Mechanistic studies and calculations reveal that ZnCl\n                    <jats:sub>2<\/jats:sub>\n                    accelerates C\u2500O bond activation, while the RuZn interface stabilizes quinone methide\u2010like intermediates through ethanol\u2010derived hydrogen transfer.\n                  <\/jats:p>","DOI":"10.1002\/adma.74805","type":"journal-article","created":{"date-parts":[[2026,8,26]],"date-time":"2026-08-26T07:41:21Z","timestamp":1787730081000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Synchronizing Lewis\u2010Acid C\u2500O Bond Activation and Ethanol\u2010Derived Hydrogen Transfer Over RuO\n                    <sub>2<\/sub>\n                    \/ZnO Carbon Aerogels for Technical Lignin Depolymerization"],"prefix":"10.1002","volume":"38","author":[{"given":"Zhengtao","family":"Wei","sequence":"first","affiliation":[{"name":"Guangdong Provincial Key Laboratory of Plant Resources Biorefinery School of Chemical Engineering and Light Industry Guangdong University of Technology  Guangzhou China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Bowen","family":"Liu","sequence":"additional","affiliation":[{"name":"Guangdong Provincial Key Laboratory of Plant Resources Biorefinery School of Chemical Engineering and Light Industry Guangdong University of Technology  Guangzhou China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Rongqi","family":"Lei","sequence":"additional","affiliation":[{"name":"Guangdong Provincial Key Laboratory of Plant Resources Biorefinery School of Chemical Engineering and Light Industry Guangdong University of Technology  Guangzhou China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhihong","family":"Cai","sequence":"additional","affiliation":[{"name":"Guangdong Provincial Key Laboratory of Plant Resources Biorefinery School of Chemical Engineering and Light Industry Guangdong University of Technology  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