{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,24]],"date-time":"2026-10-24T03:57:02Z","timestamp":1792814222285,"version":"4.5.0"},"reference-count":58,"publisher":"Wiley","issue":"59","license":[{"start":{"date-parts":[[2026,8,26]],"date-time":"2026-08-26T00:00:00Z","timestamp":1787702400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,8,26]],"date-time":"2026-08-26T00:00:00Z","timestamp":1787702400000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"content-domain":{"domain":["advanced.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Advanced Materials"],"published-print":{"date-parts":[[2026,10]]},"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    The rational design of solid\u2010state electrolytes (SSEs) with high ionic conductivity, interfacial robustness, and thermal stability remains a critical challenge for lithium metal batteries (LMBs). Herein, we established the crystal\u2010transformed hydrogen\u2010bonded organic framework\/trinuclear Cu cluster organic framework heterostructures (HOFa\/TrCuMOF\n                    <jats:sub>8<\/jats:sub>\n                    ) as thermally stable SSEs for LMBs. The crystal\u2010transformed HOF\/MOF heterostructure constructs continuous low\u2010energy Li\n                    <jats:sup>+<\/jats:sup>\n                    transport pathways, while the pendant \u2010CH\n                    <jats:sub>3<\/jats:sub>\n                    with strong steric hindrance induces anion adsorption to effectively suppress TFSI\n                    <jats:sup>\u2212<\/jats:sup>\n                    migration. Meanwhile, coordination\u2010confined TrCu synergizes with imine (C = N) groups to create a dynamically polarized local electronic environment through Li\n                    <jats:sup>+<\/jats:sup>\n                    \u2010induced charge redistribution, thereby promoting selective Li\n                    <jats:sup>+<\/jats:sup>\n                    transport. Consequently, the HOFa\/TrCuMOF\n                    <jats:sub>8<\/jats:sub>\n                    SSEs deliver a high Li\n                    <jats:sup>+<\/jats:sup>\n                    transference number (0.94) and ionic conductivity (2.7 mS cm\n                    <jats:sup>\u22121<\/jats:sup>\n                    at 30\u00b0C). Compared with polypropylene (PP) separators, the flexible HOFa\/TrCuMOF\n                    <jats:sub>8<\/jats:sub>\n                    SSEs maintain structural integrity at high temperatures (180\u00b0C), effectively suppressing electrolyte shrinkage and thermal short\u2010circuit propagation. The assembled Li|HOFa\/TrCuMOF\n                    <jats:sub>8<\/jats:sub>\n                    SSEs|LiFePO\n                    <jats:sub>4<\/jats:sub>\n                    LMBs achieve 97.8% capacity retention after 1000 cycles at 2 C and maintain stable cycling even at 100\u00b0C. Remarkably, the Li|HOFa\/TrCuMOF\n                    <jats:sub>8<\/jats:sub>\n                    SSEs|NCM811 pouch cell exhibits an impressive energy density of 259.4 Wh kg\n                    <jats:sup>\u22121<\/jats:sup>\n                    with enhanced thermal safety. This work provides a crystal\u2010transformation strategy for engineering HOF\/MOF heterostructures toward thermally stable solid\u2010state lithium batteries.\n                  <\/jats:p>","DOI":"10.1002\/adma.74814","type":"journal-article","created":{"date-parts":[[2026,8,26]],"date-time":"2026-08-26T07:06:01Z","timestamp":1787727961000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":1,"title":["Design Principles of Crystal\u2010Transformed HOF\/MOF Heterostructures for Stable Solid\u2010State Lithium Metal Batteries"],"prefix":"10.1002","volume":"38","author":[{"ORCID":"https:\/\/orcid.org\/0009-0001-2690-1902","authenticated-orcid":false,"given":"Chaofei","family":"Guo","sequence":"first","affiliation":[{"name":"Zhejiang Key Laboratory of Green and Low\u2010Carbon Utilization Technology of Agricultural and Forestry Biomass College of Chemistry and Materials Engineering Zhejiang A&amp;F University  Hangzhou P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0005-2659-6281","authenticated-orcid":false,"given":"Yingnan","family":"Cao","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Soil Pollution Control and Safety Department of Environmental Science Zhejiang University  Hangzhou Zhejiang P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiao","family":"Yu","sequence":"additional","affiliation":[{"name":"Zhejiang Key Laboratory of Green and Low\u2010Carbon Utilization Technology of Agricultural and Forestry Biomass College of Chemistry and Materials Engineering Zhejiang A&amp;F University  Hangzhou P. R. 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