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However, traditional detection methods typically include destructive processes and suffer from response delays. Near\u2010infrared (NIR) luminescent metal halides offer a novel solution to this challenge, but they still face issues such as ultraviolet excitation and low photoelectric conversion efficiency. Herein, a luminescent material was synthesized based on the blue\u2010light\u2010excited lead\u2010free perovskite Cs\n                    <jats:sub>2<\/jats:sub>\n                    HfCl\n                    <jats:sub>6<\/jats:sub>\n                    :Te\n                    <jats:sup>4+<\/jats:sup>\n                    \/Mo\n                    <jats:sup>4+<\/jats:sup>\n                    , in which energy transfer (ET) from Te\n                    <jats:sup>4+<\/jats:sup>\n                    to Mo\n                    <jats:sup>4+<\/jats:sup>\n                    enables highly efficient NIR luminescence in the 800\u20131200\u00a0nm wavelength range. Upon encapsulation with a commercial blue light chip, the fabricated NIR light\u2010emitting diode device achieved a photoelectric conversion efficiency of up to 16.1%. By utilizing the absorption characteristics of water molecules in the NIR spectrum and receiving signals via a sensor, an interactive learning process based on a neural network machine learning algorithm was employed, achieving an estimation accuracy of up to 98.6% for plant water content. This non\u2010destructive and precise NIR detection module provides a new solution for the real\u2010time monitoring of crop physiological status and holds broad application prospects in the fields of precision agriculture and plant science.\n                  <\/jats:p>","DOI":"10.1002\/adma.74821","type":"journal-article","created":{"date-parts":[[2026,8,29]],"date-time":"2026-08-29T03:53:35Z","timestamp":1787975615000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Non\u2010Destructive and High\u2010Fidelity Sensing of Plant Water Content Enabled by Near\u2010Infrared Luminescent Metal Halides"],"prefix":"10.1002","volume":"38","author":[{"given":"Yaning","family":"Zhao","sequence":"first","affiliation":[{"name":"College of Physics Science &amp; Technology Hebei University  Baoding 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