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Here, we introduce a unified catalyst architecture integrating Cu and Ni single atoms with boron\u2010, nitrogen\u2010co\u2010doped carbon (CuNi@BNC\u2010T). Heteroatom co\u2010doping stabilizes high single\u2010atom loadings, enhances metal\u2010support interactions, and suppresses carbon corrosion, while N\u2010coordinated Cu\n                    <jats:sup>+<\/jats:sup>\n                    and Ni\n                    <jats:sup>3+<\/jats:sup>\n                    sites cooperatively boost CO\n                    <jats:sub>2<\/jats:sub>\n                    RR\u2010OER, enabling ethanol formation and low\u2010overpotential OER. This strategy achieves a 0.7\u00a0V voltage gap at 5\u00a0mA cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    , 522\u00a0h cycling at 20\u00a0mA cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    , and first ethanol production via AZCBs with energy efficiency of 88% (flow\u2010cell). By elucidating previously unresolved degradation pathways, this work also correlates catalyst dynamics with battery failure, establishing design principles for durable bifunctional catalysts in aqueous Zn\u2010CO\n                    <jats:sub>2<\/jats:sub>\n                    systems.\n                  <\/jats:p>","DOI":"10.1002\/adma.74846","type":"journal-article","created":{"date-parts":[[2026,8,29]],"date-time":"2026-08-29T03:59:55Z","timestamp":1787975995000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Bifunctional Catalysis Drives Efficient and Ethanol\u2010Producing Aqueous Zn\u2010CO\n                    <sub>2<\/sub>\n                    Batteries"],"prefix":"10.1002","volume":"38","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-7253-4560","authenticated-orcid":false,"given":"Divyani","family":"Gupta","sequence":"first","affiliation":[{"name":"School of Chemical Engineering Adelaide University  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