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Here, we introduce a multicomponent assembly strategy to developed amorphous materials from \u03c0\u2010conjugated amino acids, offering a versatile platform for high\u2010performance adhesive and optical applications. The incorporation of proline\u2010based building blocks into multicomponent networks bypasses the crystallization\u2010induced self\u2010assembly that otherwise dominates in solution, thereby driving liquid\u2010liquid phase separation\u2010like pathways to yield amorphous aggregates. These aggregates exhibit exceptional thermoreversible adhesion to iron\u2010based substrates, with their densely packed architecture facilitating rarely observed excimer emission of fluorene. Furthermore, enhanced charge\u2010transfer interactions with 1,2,4,5\u2010tetracyanobenzene shift the photoluminescence from indigo to green, increase the quantum yield by orders of magnitude, and transition the emission from short\u2010lived prompt fluorescence to long\u2010lived thermally activated delayed fluorescence. Through supercooling, amorphous glasses with high hardness and optical transparency were successfully fabricated, wherein increasing the number of components enables systematic tuning of surface roughness, wettability, quantum yield, emission wavelength, and excited\u2010state lifetime. This work establishes a novel paradigm for synthesizing amorphous materials within multicomponent high\u2010entropy systems, positioning amino acid and short peptide derivatives as a versatile class of biomolecular building blocks for advanced adhesive and photonic applications.<\/jats:p>","DOI":"10.1002\/adma.74865","type":"journal-article","created":{"date-parts":[[2026,8,29]],"date-time":"2026-08-29T04:20:01Z","timestamp":1787977201000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Incorporating \u03c0\u2010Conjugated Amino Acids Into Multi\u2010Functional Amorphous Materials"],"prefix":"10.1002","volume":"38","author":[{"given":"Rong","family":"Wang","sequence":"first","affiliation":[{"name":"College of Food Science and Engineering Nanjing University of Finance and Economics\/Collaborative Innovation Center for Modern Grain Circulation and Safety\/State Key Laboratory Incubation and Development Base for Grain Quality Safety and Nutritional Health Nanjing P. 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