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Here, we design a two\u2010dimensional ordered high\u2010entropy intermetallic, HEI (PdPtRh)(InBi)ene, based on a Pd\n                    <jats:sub>1<\/jats:sub>\n                    In\n                    <jats:sub>1<\/jats:sub>\n                    \u2010type body\u2010centered\u2010cubic framework. The ordered lattice induces pronounced\n                    <jats:italic>p\u2010<\/jats:italic>\n                    \u2010\n                    <jats:italic>d<\/jats:italic>\n                    hybridization and charge redistribution, giving rise to a charge\u2010confinement effect at the active sites. Operando infrared spectroscopy, CO stripping, and theoretical calculations reveal that this confined electronic environment precisely regulates the evolution of the key poisoning intermediate *COCH\n                    <jats:sub>2<\/jats:sub>\n                    OH, weakening its accumulation while preserving efficient EG activation. As a result, HEI (PdPtRh)(InBi)ene achieves a current density of 554.21\u00a0mA cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    at 0.9\u00a0V in PET hydrolysate (PETH). Furthermore, it maintains stable operation for 90\u00a0h in a flow cell at an industrially relevant current density of 200\u00a0mA cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    , delivering an average GA Faradaic efficiency of 99.22% and an average GA production rate of 1.85\u00a0mmol h\n                    <jats:sup>\u22121<\/jats:sup>\n                    cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    . These findings demonstrate charge\u2010confinement engineering as an effective route to regulate poisoning\u2010intermediate behavior in electrocatalytic alcohol oxidation.\n                  <\/jats:p>","DOI":"10.1002\/adma.74877","type":"journal-article","created":{"date-parts":[[2026,8,31]],"date-time":"2026-08-31T13:35:45Z","timestamp":1788183345000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":2,"title":["Charge Confinement in an Ordered High\u2010Entropy Intermetallic Breaks the Activity\u2010Poisoning Trade\u2011Off for Glycolic Acid Electrosynthesis From Polyethylene Terephthalate"],"prefix":"10.1002","author":[{"given":"Ruidong","family":"Yang","sequence":"first","affiliation":[{"name":"State Key Laboratory of Green Chemical Synthesis and Conversion Zhejiang Key Laboratory of Surface and Interface Science and Engineering for Catalysts College of Chemical Engineering Zhejiang University of Technology  Hangzhou 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