{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,27]],"date-time":"2026-10-27T12:33:38Z","timestamp":1793104418975,"version":"4.5.0"},"reference-count":44,"publisher":"Wiley","issue":"60","license":[{"start":{"date-parts":[[2026,9,5]],"date-time":"2026-09-05T00:00:00Z","timestamp":1788566400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,9,5]],"date-time":"2026-09-05T00:00:00Z","timestamp":1788566400000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"content-domain":{"domain":["advanced.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Advanced Materials"],"published-print":{"date-parts":[[2026,10]]},"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    The practical application of composite solid\u2010state sodium metal batteries is critically limited by poor organic\u2013inorganic compatibility, causing particle agglomeration, high interfacial resistance, and dendrite growth. Here, a covalent surface grafting strategy constructs a multifunctional interlayer covalently anchored on Na\n                    <jats:sub>3<\/jats:sub>\n                    Zr\n                    <jats:sub>2<\/jats:sub>\n                    Si\n                    <jats:sub>2<\/jats:sub>\n                    PO\n                    <jats:sub>12<\/jats:sub>\n                    , featuring a cross\u2011linked siloxane network and terminal \u2500NH\n                    <jats:sub>2<\/jats:sub>\n                    groups. Covalent anchorage transforms inert particle surfaces into dispersible units, while \u2500NH\n                    <jats:sub>2<\/jats:sub>\n                    groups anchor TFSI\n                    <jats:sup>\u2013<\/jats:sup>\n                    and confine residual solvent via hydrogen bonding and Lewis acid\u2011base interactions. This dual regulation decouples ion transport from side reactions, yielding a high Na\n                    <jats:sup>+<\/jats:sup>\n                    transference number (0.58) and a stable, NaF\u2011rich, thin solid\u2011electrolyte interphase (SEI). The optimized electrolyte enables symmetric cells with exceptional cycling stability and high critical current density (CCD). Full cells achieve fast\u2011charging (92 mAh g\n                    <jats:sup>\u22121<\/jats:sup>\n                    at 15 C) and ultralong cycle life (76.4% retention after 7000 cycles at 10 C). A flexible pouch cell retains 97% capacity after 150 cycles. This work establishes that precise molecular\u2011level interfacial design, rather than simple physical blending, is key to high\u2011performance, dendrite\u2011resistant solid\u2011state sodium batteries.\n                  <\/jats:p>","DOI":"10.1002\/adma.74923","type":"journal-article","created":{"date-parts":[[2026,9,5]],"date-time":"2026-09-05T17:02:15Z","timestamp":1788627735000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":1,"title":["Covalently Anchored Multifunctional Interlayer Enables Ultrastable and Fast \u2010 Charging Composite Solid \u2010 State Sodium Metal Batteries"],"prefix":"10.1002","volume":"38","author":[{"given":"Shuangwu","family":"Xu","sequence":"first","affiliation":[{"name":"Hunan Provincial Key Laboratory of Chemical Power Sources College of Chemistry and Chemical Engineering Central South University  Changsha P. R. 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