{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,22]],"date-time":"2026-09-22T08:01:31Z","timestamp":1790064091126,"version":"4.0.1"},"reference-count":58,"publisher":"Wiley","license":[{"start":{"date-parts":[[2026,9,22]],"date-time":"2026-09-22T00:00:00Z","timestamp":1790035200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,9,22]],"date-time":"2026-09-22T00:00:00Z","timestamp":1790035200000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["92372116"],"award-info":[{"award-number":["92372116"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22422906"],"award-info":[{"award-number":["22422906"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100004826","name":"Natural Science Foundation of Beijing Municipality","doi-asserted-by":"publisher","award":["JQ24006"],"award-info":[{"award-number":["JQ24006"]}],"id":[{"id":"10.13039\/501100004826","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["advanced.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Advanced Materials"],"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    Layered oxide cathodes hold great promise for Na\u2010ion batteries (NIBs) but suffer from rapid performance degradation under high voltage, primarily arising from severe lattice strain, transition metal migration, and detrimental surface degradation. Here, we report a triple\u2010phase synergistic bulk\u2010surface engineering (TP\u2010SBSE) strategy that integrates a P2 phase, an O3 phase, and a surface disordered phase to address these challenges. In the bulk, guided by cationic potential control, we employ multielement composition modulation to construct a P2\/O3 biphasic structure. The interlocking effect at the biphasic interfaces effectively suppresses structural strain and mitigates volume variations under high voltage. Meanwhile, surface reconstruction yields a protective disordered phase that not only suppresses electrode\u2013electrolyte reactions but also alleviates anisotropic lattice strain, effectively inhibiting particle microcrack initiation and preserving bulk structural integrity. Owing to the TP\u2010SBSE strategy, the resulting P2\/O3\u2010Na\n                    <jats:sub>0.75<\/jats:sub>\n                    Zn\n                    <jats:sub>0.05<\/jats:sub>\n                    Ni\n                    <jats:sub>0.23<\/jats:sub>\n                    Fe\n                    <jats:sub>0.18<\/jats:sub>\n                    Mn\n                    <jats:sub>0.49<\/jats:sub>\n                    Ti\n                    <jats:sub>0.05<\/jats:sub>\n                    O\n                    <jats:sub>2<\/jats:sub>\n                    (P2\/O3\u2010NZNFMTO) cathode exhibits exceptional electrochemical performance. It delivers 80% capacity retention after 600 cycles at 1C and over 75% after 1000 cycles at 3C within 2.0 to 4.3\u00a0V, demonstrating a high rate capability and long\u2010term cycling stability. Moreover, this material exhibits enhanced thermal and air stability. This work presents a TP\u2010SBSE strategy and provides fundamental insights into developing high\u2010voltage, long\u2010life layered oxide cathodes for NIBs.\n                  <\/jats:p>","DOI":"10.1002\/adma.74956","type":"journal-article","created":{"date-parts":[[2026,9,22]],"date-time":"2026-09-22T07:09:11Z","timestamp":1790060951000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Triple\u2010Phase Synergistic Bulk\u2010Surface Engineering Enables High\u2010Rate and Long\u2010Cycling P2\/O3\u2010Based Cathode for Na\u2010Ion Batteries"],"prefix":"10.1002","author":[{"ORCID":"https:\/\/orcid.org\/0009-0003-4587-7738","authenticated-orcid":false,"given":"Peicai","family":"Li","sequence":"first","affiliation":[{"name":"State Key Laboratory of Heavy Oil Processing College of Chemistry and Chemical Engineering China University of Petroleum (East China)  Qingdao Shandong China"},{"name":"Institute of Physics 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