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Here, we report a mixed ionic\u2013electronic transduction layer (PGWL) that addresses these limitations through volumetric charge compensation. By maintaining ionic accessibility and electronic continuity within the mixed\u2010conducting network, PGWL supports a stable bulk\u2010engaged ion\u2013electron transduction mode, thereby lowering interfacial impedance while enhancing charge\u2010buffering capability against perturbations. Integrated with a body\u2010temperature\u2010activated biogel for adaptive viscoelastic adhesion and a breathable nanofibrous substrate, the electrode preserves signal integrity under sweat and mechanical interference, achieving a signal\u2010to\u2010noise ratio (SNR) of 30\u201336 dB with signal variations within 5%. We demonstrate high\u2010fidelity surface electromyography for monitoring weak neuromuscular signals during post\u2010stroke rehabilitation and long\u2010term electrocardiography (ECG) monitoring, establishing PGWL as a modular transduction layer for functionally integrated, high\u2010fidelity wearable bioelectronics.<\/jats:p>","DOI":"10.1002\/adma.74957","type":"journal-article","created":{"date-parts":[[2026,9,11]],"date-time":"2026-09-11T04:34:31Z","timestamp":1789101271000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Volumetrically Accessible Ion\u2013Electron Transduction for High\u2010Fidelity Bioelectronics"],"prefix":"10.1002","volume":"38","author":[{"given":"Jinbin","family":"Xu","sequence":"first","affiliation":[{"name":"Frontier Institute of Science and Technology (FIST) Xi'an Jiaotong University  Xi'an Shaanxi China"},{"name":"State Key Laboratory for Manufacturing Systems Engineering Xi'an 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