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Here, we report an exogenous catalyst\u2010 and solvent\u2010free one\u2010pot strategy with \u223c100% atom economy to fabricate glucose\u2010derived built\u2010in dynamic covalent thermosets from three industrial bulk feedstocks: glucose, maleic anhydride, and pentaerythritol tetrakis(3\u2010mercaptopropionate). The optimal formulation achieves an unprecedented balance between &gt;130 d of room\u2010temperature shelf life (no gelation) and 2\u2010min gelation at 150\u00b0C, delivering engineering\u2010grade tensile strength up to 113\u00a0MPa, 17.5\u00a0MPa steel lap shear strength, and drop\u2010in compatibility with industrial vacuum\u2010assisted resin infusion for large carbon fiber composite manufacturing. We demonstrate complete room\u2010temperature closed\u2010loop recycling: nondestructive recovery of high\u2010value carbon fibers with full performance retention, and matrix degradation products (73.2%\u201383.1% isolated yield) upcyclable into high\u2010performance epoxy curing agents. Thermal reprocessing provides an additional reuse pathway for manufacturing scrap. Our cradle\u2010to\u2010grave life cycle assessment confirms 81.4% lower CO\n                    <jats:sub>2<\/jats:sub>\n                    \u2010equivalent emissions than virgin bisphenol A epoxy carbon fiber composites. This work establishes a generalizable, industrially deployable paradigm for circular high\u2010performance thermosets, resolving the long\u2010standing trilemma impeding recyclable thermosets deployment.\n                  <\/jats:p>","DOI":"10.1002\/adma.74959","type":"journal-article","created":{"date-parts":[[2026,9,11]],"date-time":"2026-09-11T02:57:16Z","timestamp":1789095436000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":1,"title":["Glucose\u2010Derived Circular Thermoset Platform Breaks the Industrial Trilemma of Recyclable Structural Polymers"],"prefix":"10.1002","volume":"38","author":[{"given":"Shuaiqi","family":"Yang","sequence":"first","affiliation":[{"name":"Key Laboratory of Synthetic and Biological Colloids School of Chemical and Material Engineering Ministry of Education Jiangnan University  Wuxi P. R. 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