{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,17]],"date-time":"2026-09-17T07:03:38Z","timestamp":1789628618451,"version":"build-2803163510"},"reference-count":57,"publisher":"Wiley","license":[{"start":{"date-parts":[[2026,9,16]],"date-time":"2026-09-16T00:00:00Z","timestamp":1789516800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,9,16]],"date-time":"2026-09-16T00:00:00Z","timestamp":1789516800000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["U23B20162"],"award-info":[{"award-number":["U23B20162"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["advanced.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Advanced Materials"],"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    Ammonia, as an emerging energy carrier, holds significant strategic importance in the transition of future energy systems. Although the Haber\u2010Bosch process remains the dominant industrial route for ammonia synthesis, its high energy demand and substantial carbon emissions underscore the urgent need for sustainable alternatives. Herein, ruthenium (Ru) with an average particle size of 0.9\u00a0nm supported on BaTiO\n                    <jats:sub>3<\/jats:sub>\n                    is developed, which enables photon\u2010phonon co\u2010driven ammonia synthesis at low temperature and pressure. Photon\u2010generated electrons effectively mitigate the H\n                    <jats:sub>2<\/jats:sub>\n                    poisoning effect and more importantly remarkably promote N\n                    <jats:sub>2<\/jats:sub>\n                    adsorption and dissociation on Ru sites, thereby working together with phonons to accelerate hydrogenation along the dissociative pathway. As a result, the ammonia synthesis rate reaches 746.6\u00a0mmol\u00a0g\n                    <jats:sub>Ru<\/jats:sub>\n                    <jats:sup>\u22121<\/jats:sup>\n                    \u00a0h\n                    <jats:sup>\u22121<\/jats:sup>\n                    at 350\u00a0\u00b0C under ambient pressure and 2269\u00a0mmol\u00a0g\n                    <jats:sub>Ru<\/jats:sub>\n                    <jats:sup>\u22121<\/jats:sup>\n                    \u00a0h\n                    <jats:sup>\u22121<\/jats:sup>\n                    under 2\u00a0MPa via photon\u2010phonon co\u2010driven catalysis, representing a very low apparent activation energy of 24\u00a0kJ\u00a0mol\n                    <jats:sup>\u22121<\/jats:sup>\n                    and a 51\u2010fold improvement compared to conventional photocatalysis while maintaining reaction stability for 120\u00a0h. This work provides a novel approach toward green ammonia synthesis and opens new avenues for advancing beyond the fossil fuel driven Haber\u2010Bosch process.\n                  <\/jats:p>","DOI":"10.1002\/adma.75041","type":"journal-article","created":{"date-parts":[[2026,9,17]],"date-time":"2026-09-17T06:20:09Z","timestamp":1789626009000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Photon\u2013Phonon Co\u2010Driven Ammonia Synthesis Over Ru\/BaTiO\n                    <sub>3<\/sub>\n                    Under Very Mild Conditions"],"prefix":"10.1002","author":[{"ORCID":"https:\/\/orcid.org\/0009-0008-4078-3675","authenticated-orcid":false,"given":"Linlin","family":"Hou","sequence":"first","affiliation":[{"name":"Industrial Catalysis Center Department of Chemical Engineering Tsinghua University  Beijing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ying","family":"Liu","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Green Chemical Engineering and Industrial Catalysis Key Laboratory for Advanced Materials Centre for Computational Chemistry and Research Institute of Industrial Catalysis East China University of Science and Technology  Shanghai China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hongjie","family":"Cui","sequence":"additional","affiliation":[{"name":"Industrial Catalysis Center Department of Chemical Engineering Tsinghua University  Beijing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ziying","family":"Qin","sequence":"additional","affiliation":[{"name":"Industrial Catalysis Center Department of Chemical Engineering Tsinghua University  Beijing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Muyao","family":"Liu","sequence":"additional","affiliation":[{"name":"Industrial Catalysis Center Department of Chemical Engineering Tsinghua University  Beijing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2963-9863","authenticated-orcid":false,"given":"Lunqiao","family":"Xiong","sequence":"additional","affiliation":[{"name":"Industrial Catalysis Center Department of Chemical Engineering Tsinghua University  Beijing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yong","family":"Chen","sequence":"additional","affiliation":[{"name":"Sinopec Nanjing Research Institute of Chemical Industry Co., Ltd.  Nanjing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6138-5800","authenticated-orcid":false,"given":"Haifeng","family":"Wang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Green Chemical Engineering and Industrial Catalysis Key Laboratory for Advanced Materials Centre for Computational Chemistry and Research Institute of Industrial Catalysis East China University of Science and Technology  Shanghai China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2323-5510","authenticated-orcid":false,"given":"Junwang","family":"Tang","sequence":"additional","affiliation":[{"name":"Industrial Catalysis Center Department of Chemical Engineering Tsinghua University  Beijing China"},{"name":"State Key Lab of Chemical Engineering Department of Chemical Engineering Tsinghua University  Beijing 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