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To transcend passive physical scaffolds, we embed pure R\u2010configured enantiomers into an achiral polymer host, translating molecular chirality into configuration\u2010dependent supramolecular assembly. Unlike S\u2010enantiomeric and racemic counterparts, the R\u2010enantiomer develops more favorable configuration\u2010dependent associations with the polymer backbone via multiplexed non\u2010covalent interactions, yielding a more integrated and mechanically reinforced supramolecular network. This configuration\u2010dependent network organization facilitates Zn\n                    <jats:sup>2+<\/jats:sup>\n                    transport by establishing more continuous ion\u2010conduction pathways, successfully circumventing the racemic self\u2010quenching effect and mitigating the steric penalties of the S\u2010enantiomer. Thermodynamically, the network strictly confines highly reactive free water to eradicate parasitic reactions and block cathode dissolution. Kinetically, it reshapes the Zn\n                    <jats:sup>2+<\/jats:sup>\n                    solvation sheath and constructs sub\u2010nanoscale channels guiding homogeneous zinc deposition. Consequently, the optimized R\u2010gel symmetric cells achieve a prolonged lifespan of 5800\u00a0h. Assembled Zn||VO\n                    <jats:sub>2<\/jats:sub>\n                    full cells deliver an outstanding 91.2% capacity retention after 8000 cycles at 1\u00a0A\u00a0g\n                    <jats:sup>\u22121<\/jats:sup>\n                    , alongside robust durability (81.0% retention after 3000 cycles) at 5\u00a0A\u00a0g\n                    <jats:sup>\u22121<\/jats:sup>\n                    . This work elevates stereochemical configuration into an active structural parameter, establishing a molecularly precise design paradigm for durable AZMBs.\n                  <\/jats:p>","DOI":"10.1002\/adma.75086","type":"journal-article","created":{"date-parts":[[2026,9,18]],"date-time":"2026-09-18T05:41:30Z","timestamp":1789710090000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Chirality\u2010Engineered Supramolecular Gel Networks: Manipulating Interfacial Chemistry for Ultrastable Zinc Metal Batteries"],"prefix":"10.1002","author":[{"given":"Yiwen","family":"Zhang","sequence":"first","affiliation":[{"name":"School of Optoelectronic Science and Engineering University of Electronic Science and Technology of China  Chengdu P. R. 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