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Herein, we report a lithium\u2010induced inverted honeycomb\u2010superlattice engineering strategy that constructs a layered\u2010superlattice composite structure within NFM, resulting in a locally distributed yet long\u2010range\u2010ordered inverted honeycomb superlattice. In this structure, the transition\u2010metal (TM)\u2010dominant columns occupy the centers of hexagonal motifs, surrounded by mixed Li\/TM vertex sites. This distinctive superlattice rigidly anchors the transition\u2010metal slabs, strengthens TM\u2013O covalency, and suppresses irreversible interlayer gliding. It further regulates the high\u2010voltage structural and redox evolution by enabling highly reversible anionic oxygen redox and introducing a reversible O1 intermediate phase during cycling. Concurrently, the in situ formed Li\n                    <jats:sub>3<\/jats:sub>\n                    PO\n                    <jats:sub>4<\/jats:sub>\n                    (LP) coating effectively suppresses side reactions, further improving interfacial stability. The resulting NFM@LP cathode delivers 94.0% capacity retention after 500 cycles at 4.5\u00a0V, and the NFM@LP||hard carbon pouch full cell maintains 95.5% capacity retention over 200 cycles within 2.0\u20134.2\u00a0V. This work demonstrates that lithium\u2010induced inverted honeycomb superlattice engineering provides a promising design strategy for constructing high\u2010energy and durable O3\u2010type sodium cathodes.\n                  <\/jats:p>","DOI":"10.1002\/adma.75121","type":"journal-article","created":{"date-parts":[[2026,9,24]],"date-time":"2026-09-24T12:20:32Z","timestamp":1790252432000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Lithium\u2010Induced Inverted Honeycomb\u2010Ordered Superlattice Enables Durable O3\u2010Type Sodium Oxide Cathodes"],"prefix":"10.1002","author":[{"ORCID":"https:\/\/orcid.org\/0009-0006-3686-9228","authenticated-orcid":false,"given":"Xiaoqian","family":"Xu","sequence":"first","affiliation":[{"name":"SUSTech Energy Institute For Carbon Neutrality Department of Mechanical and Energy Engineering Southern University of Science and Technology  Shenzhen P. R. 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