{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,26]],"date-time":"2026-09-26T06:59:14Z","timestamp":1790405954105,"version":"4.1.0"},"reference-count":56,"publisher":"Wiley","license":[{"start":{"date-parts":[[2026,9,25]],"date-time":"2026-09-25T00:00:00Z","timestamp":1790294400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,9,25]],"date-time":"2026-09-25T00:00:00Z","timestamp":1790294400000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100004052","name":"King Abdullah University of Science and Technology","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100004052","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["advanced.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Advanced Materials"],"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    The long\u2010standing ethylene carbonate\u2013propylene carbonate (EC\u2013PC) disparity in graphite anodes exemplifies a broader challenge: whether solvated ions can be stripped efficiently enough to avoid solvent\u2010assisted insertion. Here, through systematic screening of commercial graphites, PC\u2010based electrolytes, and polymer binders, we show that solvent co\u2010intercalation in graphite is a system\u2010level kinetic outcome arising from competition between conventional Li\n                    <jats:sup>+<\/jats:sup>\n                    intercalation and solvent\u2010assisted insertion under galvanostatic polarization. We introduce the \u201clowest achievable potential\u201d (\n                    <jats:italic>\n                      P\n                      <jats:sub>LA<\/jats:sub>\n                    <\/jats:italic>\n                    ), a semi\u2010quantitative operational descriptor of how far a graphite\u2013electrolyte system can be polarized before PC co\u2010intercalation becomes dominant under defined testing conditions. Through integrated experimental and computational analysis, we show that the observed electrolyte\u2010dependent\n                    <jats:italic>\n                      P\n                      <jats:sub>LA<\/jats:sub>\n                    <\/jats:italic>\n                    trends arise from coupled changes in Li\n                    <jats:sup>+<\/jats:sup>\n                    solvation and interphasial chemistr\n                    <jats:italic>y<\/jats:italic>\n                    . Temperature\u2010switching and electrolyte\u2010exchange experiments indicate that neither bulk solvation nor the preformed interphase alone determines graphite stability. Instead, their relative contributions depend on the electrolyte formulation and operating conditions. Graphite surface disorder, carbon coatings, and binder chemistry provide additional electrode\u2010side regulation. These findings establish a unified kinetic framework linking bulk solvation, interfacial regulation, and operating conditions to destructive PC co\u2010intercalation.\n                  <\/jats:p>","DOI":"10.1002\/adma.75125","type":"journal-article","created":{"date-parts":[[2026,9,26]],"date-time":"2026-09-26T06:24:32Z","timestamp":1790403872000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Desolvation Kinetics Governs Propylene Carbonate Co\u2010Intercalation in Graphite Anodes"],"prefix":"10.1002","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-4574-9720","authenticated-orcid":false,"given":"Fangwang","family":"Ming","sequence":"first","affiliation":[{"name":"Center for Renewable Energy and Storage Technologies (CREST) King Abdullah University of Science and Technology (KAUST)  Thuwal Saudi Arabia"},{"name":"Materials Science and Engineering Physical Science and Engineering (PSE) Division King Abdullah University of Science and Technology (KAUST)  Thuwal Saudi Arabia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-8069-4940","authenticated-orcid":false,"given":"Simil","family":"Thomas","sequence":"additional","affiliation":[{"name":"Center for Renewable Energy and Storage Technologies (CREST) King Abdullah University of Science and Technology (KAUST)  Thuwal Saudi Arabia"},{"name":"Materials Science and Engineering Physical Science and Engineering (PSE) Division King Abdullah University of Science and Technology (KAUST)  Thuwal Saudi Arabia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Obaidah","family":"Moati","sequence":"additional","affiliation":[{"name":"Materials Science and Engineering Physical Science and Engineering (PSE) Division King Abdullah University of Science and Technology (KAUST)  Thuwal Saudi Arabia"},{"name":"Department of Chemical and Biological Engineering University of Ottawa  Ottawa Canada"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yongjiu","family":"Lei","sequence":"additional","affiliation":[{"name":"Center for Renewable Energy and Storage Technologies (CREST) King Abdullah University of Science and Technology (KAUST)  Thuwal Saudi Arabia"},{"name":"Materials Science and Engineering Physical Science and Engineering (PSE) Division King Abdullah University of Science and Technology (KAUST)  Thuwal Saudi Arabia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Dong","family":"Guo","sequence":"additional","affiliation":[{"name":"Center for Renewable Energy and Storage Technologies (CREST) King Abdullah University of Science and Technology (KAUST)  Thuwal Saudi Arabia"},{"name":"Materials Science and Engineering Physical Science and Engineering (PSE) Division King Abdullah University of Science and Technology (KAUST)  Thuwal Saudi Arabia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zainab H.","family":"Alhubail","sequence":"additional","affiliation":[{"name":"Center for Renewable Energy and Storage Technologies (CREST) King Abdullah University of Science and Technology (KAUST)  Thuwal Saudi Arabia"},{"name":"Materials Science and Engineering Physical Science and Engineering (PSE) Division King Abdullah University of Science and Technology (KAUST)  Thuwal Saudi Arabia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3624-036X","authenticated-orcid":false,"given":"Mohamed Nejib","family":"Hedhili","sequence":"additional","affiliation":[{"name":"Core Labs King Abdullah University of Science and Technology (KAUST)  Thuwal Saudi Arabia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6731-8967","authenticated-orcid":false,"given":"Jehad K.","family":"El\u2010Demellawi","sequence":"additional","affiliation":[{"name":"Center for Renewable Energy and Storage Technologies (CREST) King Abdullah University of Science and Technology (KAUST)  Thuwal Saudi Arabia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3428-1002","authenticated-orcid":false,"given":"Osman M.","family":"Bakr","sequence":"additional","affiliation":[{"name":"Center for Renewable Energy and Storage Technologies (CREST) King Abdullah University of Science and Technology (KAUST)  Thuwal Saudi Arabia"},{"name":"Materials Science and Engineering Physical Science and Engineering (PSE) Division King Abdullah University of Science and Technology (KAUST)  Thuwal Saudi Arabia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8500-1130","authenticated-orcid":false,"given":"Omar F.","family":"Mohammed","sequence":"additional","affiliation":[{"name":"Center for Renewable Energy and Storage Technologies (CREST) King Abdullah University of Science and Technology (KAUST)  Thuwal Saudi Arabia"},{"name":"Materials Science and Engineering Physical Science and Engineering (PSE) Division King Abdullah University of Science and Technology (KAUST)  Thuwal Saudi Arabia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6946-8635","authenticated-orcid":false,"given":"Kang","family":"Xu","sequence":"additional","affiliation":[{"name":"SES AI Corp.  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