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However, the easy\u2010corrosion susceptibility and poor chemical stability are common bottleneck issues that affect their applications. We report a versatile electronic structure modulation strategy for low infrared (IR)\u00a0emissivity graphene by engineering the surface chemistry of precursor graphene oxide and the followed reduction\/doping process. The fabrication protocols minimize the irreparable disruption of the intrinsic graphitic structure and enable controllable assembly of nanosheets by suppressing formation of carboxyl groups. More significantly,\u00a0the convenient reduction and halogen doping effects synergistically minimize electron scattering and enhance interfacial charge transport. The low\u2010defective graphitic structure and the ordered multiscale architecture, as well as halogen doping effect, afford exceptional carrier mobility (\u223c27.1\u00a0cm\n                    <jats:sup>2<\/jats:sup>\n                    \u00a0V\n                    <jats:sup>\u22121<\/jats:sup>\n                    s\n                    <jats:sup>\u22121<\/jats:sup>\n                    ), carrier density (5.73\u00a0\u00d7\u00a010\n                    <jats:sup>20<\/jats:sup>\n                    \u00a0cm\n                    <jats:sup>\u22123<\/jats:sup>\n                    ), and electrical conductivity comparable to highly oriented pyrolytic graphite. Surprisingly, the anomalous metallic response gives the lowest IR emissivity (0.15, 8\u201314\u00a0\u00b5m) for carbon materials, comparable to MXene and traditional metallic materials. The large\u2010scale processability and outstanding long\u2010term stability under chemical conditions offer new insights for the potential infrared\u00a0applications of graphene materials.\n                  <\/jats:p>","DOI":"10.1002\/adma.75143","type":"journal-article","created":{"date-parts":[[2026,10,13]],"date-time":"2026-10-13T14:21:46Z","timestamp":1791901306000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Graphene Materials With Anomalous Infrared Emissivity Yet Superb Chemical Stability"],"prefix":"10.1002","author":[{"given":"Ping","family":"He","sequence":"first","affiliation":[{"name":"State Key Laboratory of Organic\u2010Inorganic Composites College of Materials Science and Engineering Beijing University of Chemical Technology  Beijing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Cheng Zhang","family":"Qi","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Organic\u2010Inorganic Composites College of Materials Science and Engineering Beijing University of Chemical Technology  Beijing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Meng","family":"Jin","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Organic\u2010Inorganic Composites College of Materials Science and Engineering Beijing University of Chemical Technology  Beijing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hong Fei","family":"Mu","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Organic\u2010Inorganic Composites College of Materials Science and Engineering Beijing University of Chemical Technology  Beijing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1495-7263","authenticated-orcid":false,"given":"Peng","family":"Min","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Organic\u2010Inorganic Composites College of Materials Science and Engineering Beijing University of Chemical Technology  Beijing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8357-3362","authenticated-orcid":false,"given":"Zhong\u2010Zhen","family":"Yu","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Organic\u2010Inorganic Composites College of Materials Science and Engineering Beijing University of Chemical Technology  Beijing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1156-0495","authenticated-orcid":false,"given":"Hao\u2010Bin","family":"Zhang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Organic\u2010Inorganic Composites College of Materials Science and Engineering Beijing University of Chemical Technology  Beijing 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