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Herein, we leveraged the surface free energy minimization effect of\n                    <jats:italic>n<\/jats:italic>\n                    \u2010butyl hydrophobic groups in\n                    <jats:italic>n<\/jats:italic>\n                    \u2010butyl glycidyl ether (BGE) to design a directed induction strategy, and successfully fabricated a gradient porous superhydrophilic and antireflective coating (BTKS\u20103). This effect drove the spontaneous migration of hydrophobic groups to the surface, creating a vertical concentration gradient that modulated the local chemical environment and solvent evaporation behavior during film formation, ultimately directing the formation of a gradient porous architecture. As a result, a gradient porous architecture formed spontaneously, going from a dense bottom layer to a porous top layer. Such a gradient enables stepwise refractive index matching from the glass substrate to air, boosting transmittance to 94.61%, which significantly outperforms bare glass and commercial antireflective coatings. Meanwhile, surface hydroxyl groups and nanoscale roughness endow the coating with superhydrophilicity (contact angle &lt; 10\u00b0) and self\u2010cleaning ability, along with good abrasion resistance and UV stability. Over, this work achieves synergistic optimization of optical, self\u2010cleaning, and durability properties, offering a new paradigm for high\u2010performance functional coatings on photovoltaic glass.\n                  <\/jats:p>","DOI":"10.1002\/adma.75150","type":"journal-article","created":{"date-parts":[[2026,9,25]],"date-time":"2026-09-25T05:55:39Z","timestamp":1790315739000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Hydrophobic Group\u2010Directed Self\u2010Assembly of Gradient Porous Antireflective and Superhydrophilic Coatings on Photovoltaic Glass"],"prefix":"10.1002","author":[{"given":"Ran","family":"Chen","sequence":"first","affiliation":[{"name":"College of Chemical and Biological Engineering Zhejiang Provincial Key Laboratory of Advanced Chemical Engineering Manufacture Technology Zhejiang University  Hangzhou China"},{"name":"Zhejiang Provincial Innovation Center of Advanced Chemicals 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