{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,6]],"date-time":"2026-10-06T05:55:08Z","timestamp":1791266108762,"version":"4.1.0"},"reference-count":60,"publisher":"Wiley","license":[{"start":{"date-parts":[[2026,10,5]],"date-time":"2026-10-05T00:00:00Z","timestamp":1791158400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,10,5]],"date-time":"2026-10-05T00:00:00Z","timestamp":1791158400000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22378074"],"award-info":[{"award-number":["22378074"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22408054"],"award-info":[{"award-number":["22408054"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22508047"],"award-info":[{"award-number":["22508047"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100021171","name":"Basic and Applied Basic Research Foundation of Guangdong Province","doi-asserted-by":"publisher","award":["2025A1515011939"],"award-info":[{"award-number":["2025A1515011939"]}],"id":[{"id":"10.13039\/501100021171","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["advanced.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Advanced Materials"],"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    Three\u2010dimensional (3D) architectures can stabilize lithium (Li) metal anodes (LMAs) by mitigating localized charge accumulation and volume fluctuation, but the enlarged anode\/electrolyte interfaces aggravate parasitic reactions and unstable solid electrolyte interphase (SEI) evolution. In this study, we constructed a mass\u2010charge regulatory microdomain\u2010functionalized LMA (MCRM\u2010Li) by mechanically integrating a hierarchically structured NiS\n                    <jats:italic>\n                      <jats:sub>x<\/jats:sub>\n                    <\/jats:italic>\n                    framework with Li foil to address this structure\u2010interface dilemma. The embedded conductive matrix partitions bulk Li into ordered microdomains and establishes an interconnected electron transport network to dissipate localized current density. Simultaneously, the in situ formed Li\n                    <jats:sub>2<\/jats:sub>\n                    S\u2010rich interphase suppresses solvent attack and induces Li\n                    <jats:sub>2<\/jats:sub>\n                    S\/LiF\u2010enriched SEI formation during cycling, thereby homogenizing Li\n                    <jats:sup>+<\/jats:sup>\n                    flux and facilitating interfacial Li\n                    <jats:sup>+<\/jats:sup>\n                    diffusion. Consequently, the symmetric cell based on MCRM\u2010Li delivers an ultralong lifespan of over 5380\u00a0h with dendrite\u2010free Li deposition. Moreover, LiFePO\n                    <jats:sub>4<\/jats:sub>\n                    full cells retain 94.1% capacity after 1000 cycles at 2 C. This work provides a coupled structural\u2010interfacial design paradigm for durable lithium metal batteries through regional control of electric\u2010field distribution and interfacial mass transfer in operating 3D LMAs.\n                  <\/jats:p>","DOI":"10.1002\/adma.75218","type":"journal-article","created":{"date-parts":[[2026,10,6]],"date-time":"2026-10-06T05:30:12Z","timestamp":1791264612000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Mass\u2010Charge Regulatory Microdomains Enable Coupled Structural and Interfacial Stabilization of Durable 3D Lithium Metal Anodes"],"prefix":"10.1002","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-3924-7417","authenticated-orcid":false,"given":"Jiajie","family":"Pan","sequence":"first","affiliation":[{"name":"School of Materials and Energy Guangdong University of Technology  Guangzhou China"},{"name":"Guangzhou Key Laboratory of Clean Transportation Energy Chemistry Guangdong Provincial Key Laboratory of Plant Resources Biorefinery School of Chemical Engineering and Light Industry Guangdong University of Technology  Guangzhou China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jieying","family":"Hua","sequence":"additional","affiliation":[{"name":"Guangzhou Key Laboratory of Clean Transportation Energy Chemistry Guangdong Provincial Key Laboratory of Plant Resources Biorefinery School of Chemical Engineering and Light Industry Guangdong University of Technology  Guangzhou China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yusi","family":"Wang","sequence":"additional","affiliation":[{"name":"Guangzhou Key Laboratory of Clean Transportation Energy Chemistry Guangdong Provincial Key Laboratory of Plant Resources Biorefinery School of Chemical Engineering and Light Industry Guangdong University of Technology  Guangzhou China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Haoan","family":"Yuan","sequence":"additional","affiliation":[{"name":"Guangzhou Key Laboratory of Clean Transportation Energy Chemistry Guangdong Provincial Key Laboratory of Plant Resources Biorefinery School of Chemical Engineering and Light Industry Guangdong University of Technology  Guangzhou China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Junhao","family":"Li","sequence":"additional","affiliation":[{"name":"School of Environmental and Chemical Engineering Foshan University  Foshan China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1900-2327","authenticated-orcid":false,"given":"Kaixiang","family":"Shi","sequence":"additional","affiliation":[{"name":"Guangzhou Key Laboratory of Clean Transportation Energy Chemistry Guangdong Provincial Key Laboratory of Plant Resources Biorefinery School of Chemical Engineering and Light Industry Guangdong University of Technology  Guangzhou China"},{"name":"Jieyang Branch of Chemistry and Chemical Engineering Guangdong Laboratory (Rongjiang Laboratory)  Jieyang P. 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