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However, their performance in thin\u2010film architectures is constrained by low effective density, severe light scattering, and insufficient thermal stability. Here, we report a solution\u2010processed epitaxial growth strategy to fabricate large\u2010area, monolithic metal\u2013organic framework (MOF) thin\u2010film scintillators for temperature\u2010adaptive, high\u2010resolution X\u2010ray imaging. Mechanistic investigation reveals that surface hydroxyl\u2010mediated, molecularly oriented epitaxial growth reconstructs the interfacial energy landscape, enabling optically continuous, densely packed terbium\u2013terephthalate (Tb\u2010BDC) films on solid substrates. The Tb\u2010BDC scintillator demonstrates a light yield of 44,380 photons MeV\n                    <jats:sup>\u22121<\/jats:sup>\n                    and exceptional thermal stability in scintillation performance. At 513\u00a0K, it retains 95.2% of its room\u2010temperature radioluminescence intensity, surpassing the 42.6% retained by commercial Gd\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>2<\/jats:sub>\n                    S:Tb. Furthermore, it maintains 93.7% of its initial radioluminescence intensity following cumulative X\u2010ray irradiation up to 67.4\u00a0Gy. Notably, its radioluminescence intensity remains within 3.6% of the pristine value after 24\u00a0h immersion in water. By integrating self\u2010supervised machine learning\u2010assisted image reconstruction, temperature\u2010adaptive X\u2010ray imaging with a spatial resolution of 21.7\u00a0lp\u00a0mm\n                    <jats:sup>\u22121<\/jats:sup>\n                    is achieved. This work establishes an epitaxial microstructural design paradigm for solution\u2010processed scintillator screens operating under demanding thermal conditions.\n                  <\/jats:p>","DOI":"10.1002\/adma.75236","type":"journal-article","created":{"date-parts":[[2026,10,2]],"date-time":"2026-10-02T07:36:33Z","timestamp":1790926593000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Epitaxial Growth of Metal\u2013Organic Framework Thin\u2010Film Scintillators for Temperature\u2010Adaptive, High\u2010Resolution X\u2010Ray Imaging"],"prefix":"10.1002","author":[{"given":"Xiaoze","family":"Wang","sequence":"first","affiliation":[{"name":"State Key Laboratory of Green and Efficient Development of Phosphorus Resources New Cornerstone Science Laboratory College of Chemistry Fuzhou University  Fuzhou China"},{"name":"Institute of Biopharmaceutical and Health Engineering Tsinghua Shenzhen International Graduate 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