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Traditional modification strategies struggle to suppress phase transitions at their thermodynamic root cause, while the ideal solid\u2010solution reaction paradigm faces the challenge of difficult\u2010to\u2010control electronic structures. A novel physical paradigm was proposed that drives the solid\u2010solution\u2010dominated reaction by reshaping the electronic state through a quenching process herein. A locally disordered layered oxide, K\n                    <jats:sub>0.5<\/jats:sub>\n                    (Mn\n                    <jats:sub>0.85<\/jats:sub>\n                    Fe\n                    <jats:sub>0.1<\/jats:sub>\n                    Ti\n                    <jats:sub>0.05<\/jats:sub>\n                    )\n                    <jats:sub>0.99<\/jats:sub>\n                    (V\n                    <jats:sub>TM<\/jats:sub>\n                    B\n                    <jats:sub>i<\/jats:sub>\n                    )\n                    <jats:sub>0.01<\/jats:sub>\n                    O\n                    <jats:sub>2<\/jats:sub>\n                    (KMFTB), was constructed through a quenching\u2010assisted vacancy\u2010mediated boron (B) incorporation process, in which TM vacancies (V\n                    <jats:sub>TM<\/jats:sub>\n                    ) capture B\n                    <jats:sub>i<\/jats:sub>\n                    and reconstruct the local coordination into stable [BO\n                    <jats:sub>4<\/jats:sub>\n                    ] units. Experiments and theoretical calculations confirm that the synergistic interaction between the locally disordered structure and strong B\u2500O bonds not only stabilizes the transition metal framework through the pinning effect, but also induces a significant band broadening and electronic delocalization. This electronic structure restructuring enables KMFTB to suppress destructive phase transitions and achieve a highly reversible solid\u2010solution\u2010dominated reaction pathway, providing profound theoretical insights for the rational design of high\u2010performance cathode materials.\n                  <\/jats:p>","DOI":"10.1002\/adma.75238","type":"journal-article","created":{"date-parts":[[2026,10,2]],"date-time":"2026-10-02T03:03:16Z","timestamp":1790910196000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Solid\u2010Solution Reactions in Layer\u2010Structured Oxide Cathodes Driven by Local Disorder and Electron Delocalization"],"prefix":"10.1002","author":[{"given":"Xuan\u2010Chen","family":"Wang","sequence":"first","affiliation":[{"name":"Institute for Energy Electrochemistry and Urban Mines Metallurgy School of Metallurgy Northeastern University  Shenyang Liaoning 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