{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,5]],"date-time":"2026-10-05T07:54:23Z","timestamp":1791186863092,"version":"4.1.0"},"reference-count":37,"publisher":"Wiley","license":[{"start":{"date-parts":[[2026,10,5]],"date-time":"2026-10-05T00:00:00Z","timestamp":1791158400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,10,5]],"date-time":"2026-10-05T00:00:00Z","timestamp":1791158400000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["U22A20241"],"award-info":[{"award-number":["U22A20241"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["52200094"],"award-info":[{"award-number":["52200094"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100011282","name":"State Key Joint Laboratory of Environmental Simulation and Pollution Control","doi-asserted-by":"publisher","award":["24K20ESPCT"],"award-info":[{"award-number":["24K20ESPCT"]}],"id":[{"id":"10.13039\/501100011282","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["advanced.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Advanced Materials"],"abstract":"ABSTRACT<\/jats:title>\n \n The edge\u2010distributed metal sites are potential for efficient hydrogen peroxide (H\n 2<\/jats:sub>\n O\n 2<\/jats:sub>\n ) electrosynthesis due to their excellent intrinsic activity, but simultaneously achieving high catalytic activity and durability remains challenging. Herein, we propose an electron reservoir strategy by integrating Al\u2010based nanoclusters to stabilize edge\u2010hosted Al atomic sites (Al\n NCs<\/jats:sub>\n \/Al\n 1<\/jats:sub>\n \u2010O\u2010C@edge), enabling efficient H\n 2<\/jats:sub>\n O\n 2<\/jats:sub>\n electrosynthesis at ampere\u2010level current. The Al\n NCs<\/jats:sub>\n \/Al\n 1<\/jats:sub>\n \u2010O\u2010C@edge delivers a direct outlet H\n 2<\/jats:sub>\n O\n 2<\/jats:sub>\n concentration of 7.53\u00a0wt% and a mass\u2010normalized production rate reaching 60.1\u00a0mol\u00a0h\n \u22121<\/jats:sup>\n \u00a0g\n cat.<\/jats:sub>\n \u22121<\/jats:sup>\n at 1.6\u00a0A\u00a0cm\n \u22122<\/jats:sup>\n . The Al\n NCs<\/jats:sub>\n \/Al\n 1<\/jats:sub>\n \u2010O\u2010C@edge can be operated at currents of 1\u201310\u00a0A in a 10 \u00d7 10\u00a0cm\n 2<\/jats:sup>\n reactor, and maintains excellent long\u2010term stability for 240\u00a0h. DFT calculations, durability tests, and in situ analysis demonstrate that the Al\u2010based nanoclusters act as electron reservoirs, enabling a compressed redox swing of single atom Al centers by regulating the electron accumulation\u2010release process, which sustains key *OOH intermediate generation. Moreover, coupling H\n 2<\/jats:sub>\n O\n 2<\/jats:sub>\n synthesis with waste plastic upcycling lowers the cell voltage from 7.2\u00a0V to 6.1\u00a0V at 300\u00a0mA\u00a0cm\n \u22122<\/jats:sup>\n , while sustaining Faradaic efficiencies above 90% for both H\n 2<\/jats:sub>\n O\n 2<\/jats:sub>\n and glycolic acid production. Techno\u2010economic analysis reveals a substantially higher revenue for the coupled system than the conventional system, demonstrating its economic and environmental superiority for sustainable chemical co\u2010production.\n <\/jats:p>","DOI":"10.1002\/adma.75252","type":"journal-article","created":{"date-parts":[[2026,10,5]],"date-time":"2026-10-05T07:25:03Z","timestamp":1791185103000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Electron Reservoir\u2010Modulated Edge Hosted Sites for Ampere\u2010Level H\n 2<\/sub>\n O\n 2<\/sub>\n Production and Simultaneous Waste Plastic Upcycling"],"prefix":"10.1002","author":[{"given":"Hongxiang","family":"Li","sequence":"first","affiliation":[{"name":"College of Environmental Science and Engineering North China Electric Power University Beijing 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