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However, current research on selectivity remains focused on atomic\u2010level active sites, while often neglecting the vital influence of mesoscopic mass transport from electrode structures. Herein, we utilize the lanthanide (La) mediated interfacial electric field strategy to regulate ion deposition behavior, enabling the controllable synthesis of catalyst mesostructures. In situ spectroscopic characterization combined with multiscale simulations comprehensively elucidates the dynamic mechanism of the electrodeposition process. The low\u2010La\u2010doped Ni\u2010based catalyst (La\u2010Ni NSs) features a flat surface with oxygen\u2010affinity sites, enabling tailored urea adsorption configurations and optimized mesoscopic mass transport during UOR, and thus realizing efficient dynamic cycling of urea and OH\n                    <jats:sup>\u2212<\/jats:sup>\n                    at the catalyst's surface active sites for boosted UOR selectivity. Consequently, utilizing the high UOR selectivity of this material to assemble a membraneless electrolytic cell, which sustained a stable current density of 1.0 A cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    at just 1.7\u00a0V for over 1500\u00a0h. This work develops a La\u2010mediated mesostructuring strategy to achieve highly efficient electrocatalytic selectivity by regulating the dynamic competition of reactants in electrocatalytic systems via mesoscopic mass transport.\n                  <\/jats:p>","DOI":"10.1002\/adma.75253","type":"journal-article","created":{"date-parts":[[2026,10,8]],"date-time":"2026-10-08T10:03:06Z","timestamp":1791453786000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["La\u2010Mediated Interfacial Electric Field Effect Steers Mesoscopic Mass Transport for Highly Selective Urea Oxidation"],"prefix":"10.1002","author":[{"given":"Jing","family":"Jin","sequence":"first","affiliation":[{"name":"State Key Laboratory of Natural Product Chemistry College of Chemistry and Chemical Engineering Frontiers Science Centre for Rare Isotopes Lanzhou University  Lanzhou P. R. 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