{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,9]],"date-time":"2026-10-09T08:49:28Z","timestamp":1791535768171,"version":"4.3.4"},"reference-count":65,"publisher":"Wiley","license":[{"start":{"date-parts":[[2026,10,9]],"date-time":"2026-10-09T00:00:00Z","timestamp":1791504000000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,10,9]],"date-time":"2026-10-09T00:00:00Z","timestamp":1791504000000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22409194"],"award-info":[{"award-number":["22409194"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["advanced.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Advanced Materials"],"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    Manipulating the electric double layer (EDL) structure at nanoscale remains largely underexplored yet extremely challenging for practical Ah\u2010level aqueous zinc\u2010ion batteries (AZIBs). Here, we construct a heterogeneous nanostructured EDL with intrinsic ion\u2010transport pathways via cation\u2010anion coordination strategy, which synergistically enhances the thermodynamic stability and kinetic reversibility of the Zn anode. In\u2010situ characterizations and theoretical simulations demonstrate that the long\u2010chain ionic additive triggers the interfacial ion rearrangement and assembly within the EDL, where hydrophobic carbon chains self\u2010aggregate into dense apolar nanodomains, and cationic groups electrostatically attract anions and co\u2010assemble to form interconnected polar nanodomains. This uniquely heterogeneous EDL thermodynamically confines H\n                    <jats:sub>2<\/jats:sub>\n                    O activity and efficiently inhibits side reactions. Meanwhile, the interconnected polar ion\u2010transport pathways accelerate Zn\n                    <jats:sup>2+<\/jats:sup>\n                    migration and desolvation kinetics, achieving an ultrahigh Zn\n                    <jats:sup>2+<\/jats:sup>\n                    transference number (0.89) and dendrite\u2010free Zn deposition. Consequently, Zn\/\/Zn cell delivers stable cycling over 1,200 h (25\u00a0mA cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    , 12.5 mAh cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    ) and Zn\/\/NVO full cell retains 100% capacity after 30,000 cycles at 5 A g\n                    <jats:sup>\u22121<\/jats:sup>\n                    . Furthermore, 0.2\u2010Ah and 1.1\u2010Ah pouch cells exhibit stable operation for 2,500 and 257 cycles, respectively. This work establishes a new paradigm for EDL nanostructure engineering, advancing practical AZIBs.\n                  <\/jats:p>","DOI":"10.1002\/adma.75267","type":"journal-article","created":{"date-parts":[[2026,10,9]],"date-time":"2026-10-09T07:59:47Z","timestamp":1791532787000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Heterogeneous Electric Double Layer with Ion\u2010Transport Pathways for Practical Zinc\u2010Ion Batteries"],"prefix":"10.1002","author":[{"given":"Siqi","family":"Qin","sequence":"first","affiliation":[{"name":"Tianjin Key Laboratory of Materials Laminating Fabrication and Interface Control Technology School of Materials Science and Engineering Hebei University of Technology  Tianjin China"},{"name":"Power Battery &amp; Systems Research Center State Key Laboratory of Catalysis Dalian Institute of Chemical Physics Chinese Academy of Sciences  Dalian China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Mi","family":"Xu","sequence":"additional","affiliation":[{"name":"Power Battery &amp; Systems Research Center State Key Laboratory of Catalysis Dalian Institute of Chemical Physics Chinese Academy of Sciences  Dalian China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0003-8310-7494","authenticated-orcid":false,"given":"Jingshuai","family":"Li","sequence":"additional","affiliation":[{"name":"Power Battery &amp; Systems Research Center State Key Laboratory of Catalysis Dalian Institute of Chemical Physics Chinese Academy of Sciences  Dalian China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chunyong","family":"Liang","sequence":"additional","affiliation":[{"name":"Tianjin Key Laboratory of Materials Laminating Fabrication and Interface Control Technology School of Materials Science and Engineering Hebei University of Technology  Tianjin 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