{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,5]],"date-time":"2026-10-05T07:54:00Z","timestamp":1791186840863,"version":"4.1.0"},"reference-count":43,"publisher":"Wiley","license":[{"start":{"date-parts":[[2026,10,5]],"date-time":"2026-10-05T00:00:00Z","timestamp":1791158400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,10,5]],"date-time":"2026-10-05T00:00:00Z","timestamp":1791158400000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["52473171"],"award-info":[{"award-number":["52473171"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["52321002"],"award-info":[{"award-number":["52321002"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100012166","name":"National Key Research and Development Program of China","doi-asserted-by":"publisher","award":["2024YFF0505200"],"award-info":[{"award-number":["2024YFF0505200"]}],"id":[{"id":"10.13039\/501100012166","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100012226","name":"Fundamental Research Funds for the Central Universities","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100012226","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["advanced.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Advanced Materials"],"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    The rapid synthesis and scalable design strategies of high\u2010reliability multi\u2010dimensional and multi\u2010topological covalent organic frameworks (MDT COFs) are of great significance for meeting the diverse technological application requirements with highly differential specific demands, especially in neuromorphic electronics. Here, we introduce aniline into a sonochemical synthesis platform, where thermodynamic\u2010kinetic synergistic control expands topological diversity and substrate compatibility. We synthesized 37 COFs covering 1D to 3D, including 10 previously unreported frameworks. Relying on a parallel optimization strategy involving geometric\u2010electronic co\u2010engineering, a 3D TAPPFe\u2010Cu\n                    <jats:sub>3<\/jats:sub>\n                    COF\u2010based wafer\u2010scale memristor incorporating multiple metal and redox centers is designed and applied to shortest\u2010path optimization in the Shanghai metro network, exhibiting an 80.1% reduction in energy consumption, 78.6% faster synaptic weight reset, and a 9.36\u2010fold improvement in TDDB lifetime compared with state\u2010of\u2010the\u2010art COF\u2010based devices. This synthetic methodology and material design strategy provide a robust foundation for application\u2010tailored high\u2010reliability COFs, while opening new avenues for diversified utilization of MDT COFs.\n                  <\/jats:p>","DOI":"10.1002\/adma.75275","type":"journal-article","created":{"date-parts":[[2026,10,5]],"date-time":"2026-10-05T07:25:01Z","timestamp":1791185101000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Wafer\u2010Scale Multidimensional\u2010Topology COFs for Highly Reliable Neuromorphic Electronics"],"prefix":"10.1002","author":[{"ORCID":"https:\/\/orcid.org\/0009-0008-1572-1202","authenticated-orcid":false,"given":"Zhang","family":"Qiongshan","sequence":"first","affiliation":[{"name":"Key Laboratory for Advanced Materials School of Chemistry and Molecular Engineering East China University of Science and Technology  Shanghai China"},{"name":"Shanghai Key Laboratory of Intelligent Sensing and Detection Institute of Intelligent Sensing and Instruments East China University of Science and Technology  Shanghai China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Che","family":"Qiang","sequence":"additional","affiliation":[{"name":"Key Laboratory for Advanced Materials School of Chemistry and Molecular Engineering East China University of Science and Technology  Shanghai China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhao","family":"Lei","sequence":"additional","affiliation":[{"name":"Key Laboratory for Advanced Materials School of Chemistry and Molecular Engineering East China University of Science and Technology  Shanghai China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Wang","family":"Hao","sequence":"additional","affiliation":[{"name":"Key Laboratory for Advanced Materials School of Chemistry and Molecular Engineering East China University of Science and Technology  Shanghai China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xuan","family":"Fuzhen","sequence":"additional","affiliation":[{"name":"Shanghai Key Laboratory of Intelligent Sensing and Detection Institute of Intelligent Sensing and Instruments East China University of Science and Technology  Shanghai China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9587-6229","authenticated-orcid":false,"given":"Zhang","family":"Bin","sequence":"additional","affiliation":[{"name":"Key Laboratory for Advanced Materials School of Chemistry and Molecular Engineering East China University of Science and Technology  Shanghai China"},{"name":"Shanghai Key Laboratory of Intelligent Sensing and Detection Institute of Intelligent Sensing and Instruments East China University of Science and Technology  Shanghai China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,10,5]]},"reference":[{"key":"e_1_2_9_2_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202512521"},{"key":"e_1_2_9_3_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202502536"},{"key":"e_1_2_9_4_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41563\u2010021\u201001052\u2010w"},{"key":"e_1_2_9_5_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010025\u201058337\u2010w"},{"key":"e_1_2_9_6_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5c11454"},{"key":"e_1_2_9_7_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010024\u201055430\u20104"},{"key":"e_1_2_9_8_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41563\u2010025\u201002281\u2010z"},{"key":"e_1_2_9_9_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.nanoen.2024.110073"},{"key":"e_1_2_9_10_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.4c00950"},{"key":"e_1_2_9_11_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.chempr.2021.08.015"},{"key":"e_1_2_9_12_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsnano.4c16302"},{"key":"e_1_2_9_13_1","doi-asserted-by":"publisher","DOI":"10.1039\/D4CS00703D"},{"key":"e_1_2_9_14_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5c01434"},{"key":"e_1_2_9_15_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.4c07780"},{"key":"e_1_2_9_16_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202523595"},{"key":"e_1_2_9_17_1","doi-asserted-by":"publisher","DOI":"10.1038\/s44160\u2010025\u201000895\u20104"},{"key":"e_1_2_9_18_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010022\u201028643\u20108"},{"key":"e_1_2_9_19_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010023\u201041555\u20105"},{"key":"e_1_2_9_20_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010025\u201057892\u20106"},{"key":"e_1_2_9_21_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010021\u201024842\u2010x"},{"key":"e_1_2_9_22_1","doi-asserted-by":"publisher","DOI":"10.1038\/s44160\u2010021\u201000005\u20100"},{"key":"e_1_2_9_23_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.2c02666"},{"key":"e_1_2_9_24_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.aat7679"},{"key":"e_1_2_9_25_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.4c14535"},{"key":"e_1_2_9_26_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202511083"},{"key":"e_1_2_9_27_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.4c10071"},{"key":"e_1_2_9_28_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202412420"},{"key":"e_1_2_9_29_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.4c16678"},{"key":"e_1_2_9_30_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.3c10691"},{"key":"e_1_2_9_31_1","doi-asserted-by":"publisher","DOI":"10.1038\/s43586\u2010022\u201000181\u2010z"},{"key":"e_1_2_9_32_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.4c00369"},{"key":"e_1_2_9_33_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202409926"},{"key":"e_1_2_9_34_1","doi-asserted-by":"publisher","DOI":"10.1093\/nsr\/nwae322"},{"key":"e_1_2_9_35_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202402911"},{"key":"e_1_2_9_36_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010021\u201022243\u20108"},{"key":"e_1_2_9_37_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202413311"},{"key":"e_1_2_9_38_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202409904"},{"key":"e_1_2_9_39_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5c19922"},{"key":"e_1_2_9_40_1","doi-asserted-by":"publisher","DOI":"10.1109\/T\u2010ED.1969.16754"},{"key":"e_1_2_9_41_1","unstructured":"M.WhiteandJ.Bernstein Microelectronics Reliability: Physics\u2010of\u2010Failure Based Modeling and Lifetime Evaluation (NASA Technical Publication 2008) 2150 https:\/\/doi.org\/10.13140\/RG.2.1.2490.1281."},{"key":"e_1_2_9_42_1","doi-asserted-by":"publisher","DOI":"10.1007\/978-1-4614-1812-2_9"},{"key":"e_1_2_9_43_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41578\u2010024\u201000661\u20106"},{"key":"e_1_2_9_44_1","doi-asserted-by":"publisher","DOI":"10.20517\/ss.2025.153"}],"container-title":["Advanced Materials"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/advanced.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/adma.75275","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/advanced.onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/adma.75275","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/advanced.onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/adma.75275","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,10,5]],"date-time":"2026-10-05T07:25:05Z","timestamp":1791185105000},"score":1,"resource":{"primary":{"URL":"https:\/\/advanced.onlinelibrary.wiley.com\/doi\/10.1002\/adma.75275"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,10,5]]},"references-count":43,"alternative-id":["10.1002\/adma.75275"],"URL":"https:\/\/doi.org\/10.1002\/adma.75275","archive":["Portico"],"relation":{},"ISSN":["0935-9648","1521-4095"],"issn-type":[{"value":"0935-9648","type":"print"},{"value":"1521-4095","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,10,5]]},"assertion":[{"value":"2026-05-07","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-09-28","order":2,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-10-05","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e75275"}}