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Herein, rare\u2010earth metal Pr\u2010based single\u2010atom nano\u2010stabilizer engineering is reported for stabilizing highly active Fe\u2010N\n                    <jats:sub>4<\/jats:sub>\n                    O sites, thereby achieving enhanced activity toward the oxygen reduction reaction and in metal\u2010air batteries. In situ x\u2010ray absorption spectroscopy reveals that the axial O coordination atom of the Fe\u2010N\n                    <jats:sub>4<\/jats:sub>\n                    O site is stabilized by the Pr single\u2010atom nano\u2010stabilizer, which downshifts the d\u2010band center of Fe, facilitates the reduction and desorption of the *OH intermediate, and thus lowers the energy barrier of the rate\u2010determining step\u2014verified via density functional theory calculations. The FePr\u2010ISAS\/CN catalyst with the nano\u2010stabilizer exhibits a half\u2010wave potential of 0.921\u00a0V versus RHE, 45 and 72\u00a0mV higher than those of Fe\u2010ISAS\/CN and the commercial Pt\/C catalyst. Furthermore, the FePr\u2010ISAS\/CN\u2010based Al\u2010air battery achieves a high peak power density of 360\u00a0mW cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    , superior to most reported metal single\u2010atom catalyst\u2010based Al\u2010air batteries. This work reveals the potential of rare\u2010earth metal\u2010based nano\u2010stabilizer engineering for stabilizing the coordination structure of highly active sites and thereby boosting activity in both electrocatalytic ORR and metal\u2010air battery devices.\n                  <\/jats:p>","DOI":"10.1002\/adma.75283","type":"journal-article","created":{"date-parts":[[2026,10,4]],"date-time":"2026-10-04T07:52:36Z","timestamp":1791100356000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Nano\u2010Stabilizer Engineering of Rare\u2010Earth Metal Single\u2010Atom Site for Boosted Oxygen Electroreduction and Metal\u2010Air Batteries"],"prefix":"10.1002","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-7336-0985","authenticated-orcid":false,"given":"Shengjie","family":"Wei","sequence":"first","affiliation":[{"name":"State Key Laboratory of Materials Low\u2010Carbon Recycling Center Excellence for Environmental Safety and Biological Effects College of Chemistry and Life Science and College of Materials Science and Engineering Beijing University of Technology  Beijing P. 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