{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,5]],"date-time":"2026-10-05T07:55:17Z","timestamp":1791186917769,"version":"4.1.0"},"reference-count":39,"publisher":"Wiley","license":[{"start":{"date-parts":[[2026,10,5]],"date-time":"2026-10-05T00:00:00Z","timestamp":1791158400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,10,5]],"date-time":"2026-10-05T00:00:00Z","timestamp":1791158400000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22173046 22405121 82104110 22503047"],"award-info":[{"award-number":["22173046 22405121 82104110 22503047"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100004608","name":"Natural Science Foundation of Jiangsu Province","doi-asserted-by":"publisher","award":["BK20210691"],"award-info":[{"award-number":["BK20210691"]}],"id":[{"id":"10.13039\/501100004608","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["advanced.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Advanced Materials"],"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    Supramolecular adhesives enable on\u2010demand detachment due to their dynamic nature. However, such behavior usually at the cost of limited adhesive toughness. To promote the intrinsic compromise between adhesive toughness and switchability, we propose a soft\u2010confinement\u2010regulated nanorod crystallization strategy to construct a supramolecular elastomer (PTA\u2010PCL). The amphiphilic and soft poly (thioctic acid) (PTA) matrix forms a dynamically confined interface through hydrogen bonding, directing the oriented self\u2010assembly of hydrophobic polycaprolactone glycol (PCL\u2010OH) into nanorod crystals with an aspect ratio of 4.80 and thereby reinforcing the network. Meanwhile, thermally triggered phase transitions drive mesoscale evolution, allowing the adhesion state to be tuned by the dynamic confinement interface. Benefiting from this hierarchical structural design, the PTA\u2010PCL film exhibited robust adhesion (1609.31 J m\n                    <jats:sup>\u2212<\/jats:sup>\n                    <jats:sup>2<\/jats:sup>\n                    ), switchable debonding (83.7 J m\n                    <jats:sup>\u2212<\/jats:sup>\n                    <jats:sup>2<\/jats:sup>\n                    ; switching ratio = 14.5), and high toughness (3.35\u00a0MJ m\n                    <jats:sup>\u2212<\/jats:sup>\n                    <jats:sup>3<\/jats:sup>\n                    ). Molecular dynamics simulations indicated partial compatibility and strong interfacial interactions between PTA and PCL\u2010OH, while the synergistic coupling between interfacial enrichment and crystallization reinforcement was confirmed by low\u2010field solid\u2010state NMR. Overall, this study presents a new strategy for inducing nanorod crystallization within soft networks, and the superior switchable adhesion and interfacial toughness make PTA\u2010PCL a promising candidate for advanced adhesive materials.\n                  <\/jats:p>","DOI":"10.1002\/adma.75286","type":"journal-article","created":{"date-parts":[[2026,10,5]],"date-time":"2026-10-05T07:28:11Z","timestamp":1791185291000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Supramolecular Elastomer Based Switchable Adhesives Regulated by Soft Confinement Induced Nano\u2010Rod Crystals"],"prefix":"10.1002","author":[{"given":"Qi","family":"Jin","sequence":"first","affiliation":[{"name":"Department of Polymer Science and Engineering State Key Laboratory of Analytical Chemistry for Life Sciences Key Laboratory of High\u2010Performance Polymer Material and Technology MOE School of Chemistry Nanjing University  Nanjing People's 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Nanjing University  Nanjing People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yuyang","family":"Liu","sequence":"additional","affiliation":[{"name":"Department of Polymer Science and Engineering State Key Laboratory of Analytical Chemistry for Life Sciences Key Laboratory of High\u2010Performance Polymer Material and Technology MOE School of Chemistry Nanjing University  Nanjing People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0005-8063-1156","authenticated-orcid":false,"given":"Ziyi","family":"Wang","sequence":"additional","affiliation":[{"name":"Department of Polymer Science and Engineering State Key Laboratory of Analytical Chemistry for Life Sciences Key Laboratory of High\u2010Performance Polymer Material and Technology MOE School of Chemistry Nanjing University  Nanjing People's Republic of 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