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However, their development is hindered by the limited reversibility of Al plating\/stripping on Al metal anodes and cathode structural degradation under high\u2010voltage operation, resulting in short cycle life and limited energy density. These challenges originate from an incomplete understanding of how interphase components and properties regulate electrode reactions. Here, we systematically investigate the interphase properties in AIBs and reveal that AlF\n                    <jats:sub>3<\/jats:sub>\n                    exhibits the highest interfacial energy, mechanical strength against dendrite growth, and electrochemical stability with electron\u2010blocking capability against parasitic reactions, making it an ideal artificial interphase component. Based on these findings, AlF\n                    <jats:sub>3<\/jats:sub>\n                    \u2010enriched artificial interphases are constructed in Al||graphene batteries, enabling 99.9% Al plating\/stripping Coulombic efficiency with uniform deposition morphology. The Al||graphene full cell delivers a high specific capacity of 122.6\u00a0mAh\u00a0g\n                    <jats:sup>\u22121<\/jats:sup>\n                    , ultrahigh\u2010rate capability (817 C, charged in 2.936 s), and long\u2010term cyclability exceeding 100\u00a0000 cycles. This AlF\n                    <jats:sub>3<\/jats:sub>\n                    \u2010enriched interphase strategy establishes fundamental principles for designing high\u2010performance AIBs.\n                  <\/jats:p>","DOI":"10.1002\/adma.75287","type":"journal-article","created":{"date-parts":[[2026,10,6]],"date-time":"2026-10-06T04:14:01Z","timestamp":1791260041000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["AlF\n                    <sub>3<\/sub>\n                    \u2010Enriched Interphase Design Enables Comprehensive Electrochemical Performance Enhancement in Al\u2010Ion Batteries"],"prefix":"10.1002","author":[{"given":"Haichen","family":"Huang","sequence":"first","affiliation":[{"name":"State Key Laboratory of Crystal Materials Shandong University  Jinan People's Republic of 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Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1876-5103","authenticated-orcid":false,"given":"Jian\u2010Jun","family":"Wang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Crystal Materials Shandong University  Jinan People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1640-9620","authenticated-orcid":false,"given":"Hong","family":"Liu","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Crystal Materials Shandong University  Jinan People's Republic of China"},{"name":"Institute For Advanced Interdisciplinary Research (IAIR) School of Chemistry and Chemical Engineering University of Jinan  Jinan People's Republic of 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