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A key challenge is that preserving water mobility at low temperatures can inadvertently promote parasitic hydrogen evolution under ambient conditions. Here, we design a hydrogel electrolyte that combines a wide operating\u2010temperature window with enhanced interfacial stability through coupled thermodynamic\u2013kinetic regulation of the electrolyte environment. By disrupting the tetrahedral hydrogen\u2010bond network and diversifying local coordination environments, the hydrogel enhances configurational disorder and suppresses water crystallization. Simultaneously, restricted molecular dynamics retard ice nucleation and parasitic hydrogen evolution. This hydrogen\u2010bond architecture further promotes rapid and uniform Zn deposition by regulating the thermodynamics and kineticsof interfacial Zn\n                    <jats:sup>2+<\/jats:sup>\n                    transfer. Consequently, AZIBs achieve exceptional stability: over 8000\u00a0h in symmetric cells, 15\u00a0000 cycles in full cells, and high reversibility down to \u221230\u00b0C. This work establishes thermodynamic\u2013kinetic coupling as a promising strategy for designing high\u2010performance aqueous batteries under extreme conditions.\n                  <\/jats:p>","DOI":"10.1002\/adma.75301","type":"journal-article","created":{"date-parts":[[2026,10,7]],"date-time":"2026-10-07T06:38:26Z","timestamp":1791355106000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Thermodynamic\u2013Kinetic Coupling of Water Structure Enables Wide\u2010Temperature Zinc Batteries"],"prefix":"10.1002","author":[{"given":"Xueer","family":"Xu","sequence":"first","affiliation":[{"name":"State Key Laboratory of Silicon and Advanced Semiconductor Materials School of Materials Science and Engineering Zhejiang University  Hangzhou P. R. 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