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Solar\u2010driven photoreforming of plastic waste simultaneously generates value\u2010added chemicals, fuels, and carbon materials. Conceptually, this process resembles an artificial photosynthesis system, wherein solar energy serves as the driving force, photocatalysts function as active media, and waste plastics act as the feedstocks. However, the practical efficacy of photoreforming is limited by the extent of plastic pretreatment, the activation ability of inert C\u2500X bonds, and the selectivity toward desired products. This review focuses on the state\u2010of\u2010the\u2010art in solar\u2010driven photoreforming technologies for plastic conversion, offering a comprehensive analysis from fundamental reaction mechanisms to practical implementation. In particular, this review highlights the essential role of in situ characterization in uncovering reaction mechanisms and thereby guiding the construction of efficient reaction systems. 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