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In this work, we advance beyond conventional cationic grafting modification strategies via the rational design of fluorinated alkyl side chains on hydrophobic polymer backbones, thereby enhancing amphiphilic self\u2010assembly. Such structural engineering facilitates the formation of interconnected pathways that enable efficient hydroxide ion and water transport. The resulting PTA\n                    <jats:sub>fc<\/jats:sub>\n                    P membrane exhibits a low swelling ratio of 14.38% and an OH\n                    <jats:sup>\u2212<\/jats:sup>\n                    conductivity of 179.2\u00a0mS cm\n                    <jats:sup>\u22121<\/jats:sup>\n                    at 80\u00b0C. Notably, the establishment of an efficient alkaline electrolyte transport network enables the PTA\n                    <jats:sub>fc<\/jats:sub>\n                    P\u2010based electrolyzer to achieve a current density of 7.5 A cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    . Furthermore, the electrolyzer incorporating a PTA\n                    <jats:sub>fc<\/jats:sub>\n                    P membrane demonstrates satisfactory durability over 2000 h of operation, exhibiting a voltage fade rate of only 17.9\u00a0\u00b5V\u00a0h\n                    <jats:sup>\u22121<\/jats:sup>\n                    at 0.5\u00a0A\u00a0cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    , substantiating its application potential for industrial\u2010scale deployment.\n                  <\/jats:p>","DOI":"10.1002\/adma.75319","type":"journal-article","created":{"date-parts":[[2026,10,7]],"date-time":"2026-10-07T08:49:32Z","timestamp":1791362972000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Tailoring Fluorinated Chain Positioning in Anion Exchange Membranes for Boosted Ion and Water Transport Channels"],"prefix":"10.1002","author":[{"given":"Chengxiao","family":"Zhou","sequence":"first","affiliation":[{"name":"Jiangsu Engineering Laboratory of Novel Functional Polymeric Materials Jiangsu Key Laboratory of Advanced Negative Carbon Technologies Suzhou Key Laboratory of Soft Material and New Energy College of Chemistry Chemical Engineering and Materials Science Soochow University  Suzhou China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Tongxin","family":"Yin","sequence":"additional","affiliation":[{"name":"Jiangsu Engineering Laboratory of Novel Functional Polymeric Materials Jiangsu Key Laboratory of Advanced Negative Carbon Technologies Suzhou Key Laboratory of Soft Material and New Energy College of Chemistry Chemical Engineering and Materials Science Soochow University  Suzhou China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jinhong","family":"Shi","sequence":"additional","affiliation":[{"name":"Jiangsu Engineering Laboratory of Novel Functional Polymeric Materials Jiangsu Key Laboratory of Advanced Negative Carbon Technologies Suzhou Key Laboratory of Soft Material and New Energy College of Chemistry Chemical Engineering and Materials Science Soochow University  Suzhou China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hanchi","family":"Zhang","sequence":"additional","affiliation":[{"name":"Jiangsu Engineering Laboratory of Novel Functional Polymeric Materials Jiangsu Key Laboratory of Advanced Negative Carbon Technologies Suzhou Key Laboratory of Soft Material and New Energy College of Chemistry Chemical Engineering and Materials Science Soochow University  Suzhou China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yanyou","family":"Hua","sequence":"additional","affiliation":[{"name":"School of Rail Transportation and Intelligent Urban Rail Engineering Research Center of Jiangsu Province Soochow University  Suzhou 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