{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,15]],"date-time":"2026-10-15T08:45:11Z","timestamp":1792053911669,"version":"4.4.0"},"reference-count":58,"publisher":"Wiley","license":[{"start":{"date-parts":[[2026,10,15]],"date-time":"2026-10-15T00:00:00Z","timestamp":1792022400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by-nc\/4.0\/"},{"start":{"date-parts":[[2026,10,15]],"date-time":"2026-10-15T00:00:00Z","timestamp":1792022400000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100000780","name":"European Commission","doi-asserted-by":"publisher","award":["101287828"],"award-info":[{"award-number":["101287828"]}],"id":[{"id":"10.13039\/501100000780","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100003359","name":"Generalitat Valenciana","doi-asserted-by":"publisher","award":["CIPROM\/2024\/51"],"award-info":[{"award-number":["CIPROM\/2024\/51"]}],"id":[{"id":"10.13039\/501100003359","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100003359","name":"Generalitat Valenciana","doi-asserted-by":"publisher","award":["Ayudasparalacreaci\u00f3ndeSPIN\u2010OFFSCISPINSEM\/2026\/009"],"award-info":[{"award-number":["Ayudasparalacreaci\u00f3ndeSPIN\u2010OFFSCISPINSEM\/2026\/009"]}],"id":[{"id":"10.13039\/501100003359","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["advanced.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Advanced Materials"],"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    Metal\u2010organic frameworks (MOFs) are widely explored for gas separation, catalysis, or energy storage, yet their integration with other electronically functional materials remains largely unexplored. Here, we integrate the layered Hofmann\u2010type spin\u2010crossover (SCO) MOF {Fe\n                    <jats:sup>II<\/jats:sup>\n                    (pyS\n                    <jats:sub>2<\/jats:sub>\n                    Et)\n                    <jats:sub>2<\/jats:sub>\n                    [Pt\n                    <jats:sup>II<\/jats:sup>\n                    (CN)\n                    <jats:sub>4<\/jats:sub>\n                    ]} into electrical nanodevices to control the properties of two\u2010dimensional (2D) quantum materials. Our molecular approach exploits the stimuli\u2010responsive nature of SCO\u2010layered materials as switchable building blocks. We demonstrate selective modulation of the electronic transport in van der Waals heterostructures interfacing SCO with 2D quantum materials (few\u2010layer graphene, magnetic CrSBr, superconducting NbSe\n                    <jats:sub>2<\/jats:sub>\n                    ) through the strain induced via thermal and light\u2010induced spin transitions. In graphene, the conductivity is selectively switched by light. In spin\u2010valves based on CrSBr bilayers, the MOF triggers magnetic hysteresis (absent in pristine CrSBr) and enables tunable non\u2010volatile zero\u2010field memory. In NbSe\n                    <jats:sub>2<\/jats:sub>\n                    , light modulates the superconducting critical current and transition temperature. These results establish layered stimuli\u2010responsive SCO MOFs as active molecular control elements for 2D quantum materials, providing a route to strain\u2010mediated control of electronic, magnetic, and superconducting functionalities, and extending MOF\u2010based architectures beyond traditional porous\u2010matter applications toward multifunctional electronics and spintronics.\n                  <\/jats:p>","DOI":"10.1002\/adma.75351","type":"journal-article","created":{"date-parts":[[2026,10,15]],"date-time":"2026-10-15T07:59:52Z","timestamp":1792051192000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Layered Spin\u2010Crossover Metal\u2010Organic Frameworks for Light\u2010Induced Control of Two\u2010Dimensional Quantum Materials"],"prefix":"10.1002","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-3213-5906","authenticated-orcid":false,"given":"Carla","family":"Boix\u2010Constant","sequence":"first","affiliation":[{"name":"Instituto de Ciencia Molecular (ICMol) Universitat De Val\u00e8ncia  Paterna Spain"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Alejandro","family":"Orellana\u2010Silla","sequence":"additional","affiliation":[{"name":"Instituto de Ciencia Molecular (ICMol) Universitat De Val\u00e8ncia  Paterna Spain"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jos\u00e9 Antonio","family":"Real","sequence":"additional","affiliation":[{"name":"Instituto de Ciencia Molecular (ICMol) Universitat De Val\u00e8ncia  Paterna Spain"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6319-9238","authenticated-orcid":false,"given":"Samuel","family":"Ma\u00f1as\u2010Valero","sequence":"additional","affiliation":[{"name":"Instituto de Ciencia Molecular (ICMol) Universitat De Val\u00e8ncia  Paterna Spain"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1848-8791","authenticated-orcid":false,"given":"Eugenio","family":"Coronado","sequence":"additional","affiliation":[{"name":"Instituto de Ciencia Molecular (ICMol) Universitat De Val\u00e8ncia  Paterna 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