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To overcome this bottleneck, we herein propose a strategy for modulating the adsorption\/desorption equilibrium of N\u2010related species using precisely designed bimetallic Ni\n                    <jats:sub>1<\/jats:sub>\n                    Au\n                    <jats:sub>n<\/jats:sub>\n                    active sites supported on a strontium titanate (NiAu\u2010STO) semiconductor photocatalyst. This strategy significantly enhances N\n                    <jats:sub>2<\/jats:sub>\n                    adsorption\/activation and effective generation of N\u2010related intermediates to facilitate C\u2013N coupling for the photocatalytic urea synthesis, affording a considerable urea production rate of 1333.63\u00a0\u00b5g\u00a0g\n                    <jats:sub>cat.<\/jats:sub>\n                    <jats:sup>\u22121<\/jats:sup>\n                    , with successful crystallization of a collectible solid\u2010phase urea product. Furthermore, we developed a novel reaction\u2010temperature programmed desorption\u2010mass spectrometry tandem monitoring system to elucidate the adsorption behavior of N\n                    <jats:sub>2<\/jats:sub>\n                    , which can clarify the adsorption behavior of N\n                    <jats:sub>2<\/jats:sub>\n                    and confirm the formation of critical N\u2010related intermediates (e.g., *NH\n                    <jats:sub>2<\/jats:sub>\n                    ) on the NiAu\u2010STO photocatalyst. In addition, in situ Raman spectroscopy results further validated the formation of a distinctive C\u2013N coupling intermediate (*NH\n                    <jats:sub>2<\/jats:sub>\n                    COO\n                    <jats:sup>\u2013<\/jats:sup>\n                    ) on the photocatalyst surface, providing mechanistic insights into urea photosynthesis from N\n                    <jats:sub>2<\/jats:sub>\n                    , CO\n                    <jats:sub>2<\/jats:sub>\n                    , and H\n                    <jats:sub>2<\/jats:sub>\n                    O.\n                  <\/jats:p>","DOI":"10.1002\/adma.75416","type":"journal-article","created":{"date-parts":[[2026,10,16]],"date-time":"2026-10-16T12:07:40Z","timestamp":1792152460000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Tuning N\u2010Species Adsorption\/Desorption Equilibrium by Ni\n                    <sub>1<\/sub>\n                    Au\n                    <sub>n<\/sub>\n                    \u2010SrTiO\n                    <sub>3<\/sub>\n                    for Artificial Urea Photosynthesis"],"prefix":"10.1002","author":[{"given":"Dong","family":"Li","sequence":"first","affiliation":[{"name":"Key Laboratory of Photochemical Conversion and Optoelectronic Materials Technical Institute of Physics and Chemistry Chinese Academy of Sciences  Beijing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shaochuan","family":"Zhai","sequence":"additional","affiliation":[{"name":"Key Laboratory of Photochemical Conversion and Optoelectronic Materials Technical Institute of Physics and Chemistry Chinese Academy of Sciences  Beijing China"},{"name":"Center of Materials Science and Optoelectronics Engineering University of Chinese Academy of Sciences  Beijing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jinhu","family":"Wang","sequence":"additional","affiliation":[{"name":"Key Laboratory of Photochemical Conversion and Optoelectronic Materials Technical Institute of Physics and Chemistry Chinese Academy of Sciences  Beijing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1340-443X","authenticated-orcid":false,"given":"Junyu","family":"Gao","sequence":"additional","affiliation":[{"name":"Key Laboratory of Photochemical Conversion and Optoelectronic Materials Technical Institute of Physics and Chemistry Chinese Academy of Sciences  Beijing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ning","family":"Xu","sequence":"additional","affiliation":[{"name":"School of Life Science Tsinghua University  Beijing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chao","family":"Zhou","sequence":"additional","affiliation":[{"name":"Key Laboratory of Photochemical Conversion and Optoelectronic Materials Technical Institute of Physics and Chemistry Chinese Academy of Sciences 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