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However, designing universal hole\u2010transport\u2010layers (HTLs) compatible with diverse photovoltaic platforms remains a fundamental challenge. We propose two regioisomeric acceptor\u2013donor\u2013acceptor type self\u2010assembled molecules (SAMs) with dithienopyrrole (DTP) core. Simply swapping ortho\u2010\/para\u2010 positions of trifluoromethyl and chlorine on the phenyl termini switches molecular stacking from disordered antiparallel to well\u2010ordered parallel. This programmable assembly benefits to yield uniform HTLs on ITO with homogeneous surface potential, alongside enhanced crystallinity and vertical phase segregation in the PM6:Y6 active layer. Optimized OSCs and OPDs achieve 18.70% power conversion efficiency (PCE) and a shot\u2010noise\u2010limited specific detectivity of 6.52 \u00d7 10\n                    <jats:sup>14<\/jats:sup>\n                    Jones at 805\u00a0nm (specific detectivity: 4.26 \u00d7 10\n                    <jats:sup>13<\/jats:sup>\n                    Jones). The versatility of the optimized SAM is validated across state\u2010of\u2010the\u2010art binary\/ternary systems (PCE of 20.92% for D18:L8\u2010BO:BTP\u2010eC9 system), even upon scaling up (PCE of 19.1% for PM6:L8\u2010BO:BTP\u2010eC9 system, device area = 0.6\u00a0cm\n                    <jats:sup>2<\/jats:sup>\n                    ). This work not only elevates DTP as a competitive alternative against carbazole for SAMs, but also establishes functional group transposition as a finely tuned molecular lever that co\u2010engineers interfacial order and active\u2010layer morphology toward high\u2010performance organic optoelectronics.\n                  <\/jats:p>","DOI":"10.1002\/adma.75446","type":"journal-article","created":{"date-parts":[[2026,10,21]],"date-time":"2026-10-21T11:00:07Z","timestamp":1792580407000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Functional Group Transposition Enables Antiparallel\u2013Parallel Packing Switching in Dithieno[3,2\u2010b:2\u2032,3\u2032\u2010d]pyrrole Self\u2010Assembled Molecules for Efficient Organic Photovoltaics"],"prefix":"10.1002","author":[{"given":"Huayi","family":"Liu","sequence":"first","affiliation":[{"name":"State Key Laboratory of Chemical Resource Engineering Beijing Advanced Innovation 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