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Based on classical crystal growth theory, sluggish metal ion transport during the deposition process will lead to rapid interfacial metal ion depletion, resulting in a sharp increase in interfacial supersaturation and subsequently inducing dendrite growth. Herein, micropore high\u2010entropy single\u2010atoms carbon nanoparticles (CuNiMnCoIr\/CNs) were synthesized as a unique electrolyte additive to suppress interfacial Zn\n                    <jats:sup>2+<\/jats:sup>\n                    concentration polarization and strengthen Zn chemistry at the atomic level. The micropore CuNiMnCoIr\/CNs not only provide abundant Zn\n                    <jats:sup>2+<\/jats:sup>\n                    transport channels but significantly reduce the migration energy barrier of Zn\n                    <jats:sup>2+<\/jats:sup>\n                    from the bulk electrolyte to electrode interface to promote rapid desolvation kinetics and homogenize Zn\n                    <jats:sup>2+<\/jats:sup>\n                    flux, thereby effectively alleviating interfacial Zn\n                    <jats:sup>2+<\/jats:sup>\n                    supersaturation and guiding layer\u2010by\u2010layer Zn deposition. Consequently, trace CuNiMnCoIr\/CNs additive delivers a high Zn\n                    <jats:sup>2+<\/jats:sup>\n                    transference number of 0.89 and enables Zn\/\/Zn cells to cycle stably for over 4000\u00a0h at 5\u00a0mA\u00a0cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    , and 800\u00a0h even at 50\u00a0mA\u00a0cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    , with an outstanding cumulative deposition capacity up to 20 Ah cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    . Such knowledge may provide new insights to challenge interface chemistry for advanced aqueous metal\u2010ion batteries.\n                  <\/jats:p>","DOI":"10.1002\/adma.75467","type":"journal-article","created":{"date-parts":[[2026,10,21]],"date-time":"2026-10-21T11:17:34Z","timestamp":1792581454000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Atomic\u2010Level Regulating Layer\u2010by\u2010Layer Zinc Deposition by High\u2010Entropy Single\u2010Atoms Electrolyte Additive"],"prefix":"10.1002","author":[{"given":"Xiude","family":"Liu","sequence":"first","affiliation":[{"name":"Department of Polymeric Materials &amp; Engineering College of Materials &amp; Metallurgy Guizhou University  Guiyang China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jinlong","family":"Zhang","sequence":"additional","affiliation":[{"name":"Department of Polymeric Materials &amp; Engineering College of Materials 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