{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,25]],"date-time":"2026-09-25T19:54:35Z","timestamp":1790366075393,"version":"4.1.0"},"reference-count":83,"publisher":"Wiley","issue":"15","license":[{"start":{"date-parts":[[2020,6,29]],"date-time":"2020-06-29T00:00:00Z","timestamp":1593388800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100002428","name":"Austrian Science Fund","doi-asserted-by":"publisher","award":["P26264"],"award-info":[{"award-number":["P26264"]}],"id":[{"id":"10.13039\/501100002428","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["advanced.onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Adv Synth Catal"],"published-print":{"date-parts":[[2020,8,4]]},"abstract":"<jats:title>Abstract<\/jats:title><jats:p>Three molybdenum(VI) dioxido complexes [MoO<jats:sub>2<\/jats:sub>(L)<jats:sub>2<\/jats:sub>] bearing Schiff base ligands were reacted with B(C<jats:sub>6<\/jats:sub>F<jats:sub>5<\/jats:sub>)<jats:sub>3<\/jats:sub> to afford the corresponding adducts [MoO{OB(C<jats:sub>6<\/jats:sub>F<jats:sub>5<\/jats:sub>)<jats:sub>3<\/jats:sub>}(L)<jats:sub>2<\/jats:sub>], which were fully characterized. They exhibit Frustrated Lewis\u2010Pairs reactivity when reacting with silanes. Especially, the [MoO{OB(C<jats:sub>6<\/jats:sub>F<jats:sub>5<\/jats:sub>)<jats:sub>3<\/jats:sub>}(L)<jats:sub>2<\/jats:sub>] complex with L=2,4\u2010dimethyl\u20106\u2010((phenylimino)methyl)phenol proved to be active as catalyst for the hydroalkylation of aryl alkenes with organohalides and for the Atom\u2010Transfer Radical Addition (ATRA) of organohalides to aliphatic alkenes. A series of <jats:italic>gem<\/jats:italic>\u2010dichloride and <jats:italic>gem<\/jats:italic>\u2010dibromide compounds with potential for further derivatization were synthesized from simple alkenes and organohalides, like chloroform or bromoform, using low catalyst loading.<\/jats:p><jats:p><jats:boxed-text content-type=\"graphic\" position=\"anchor\"><jats:graphic xmlns:xlink=\"http:\/\/www.w3.org\/1999\/xlink\" mimetype=\"image\/png\" position=\"anchor\" specific-use=\"enlarged-web-image\" xlink:href=\"graphic\/adsc202000425-toc-0001-m.png\"><jats:alt-text>magnified image<\/jats:alt-text><\/jats:graphic><\/jats:boxed-text>\n<\/jats:p>","DOI":"10.1002\/adsc.202000425","type":"journal-article","created":{"date-parts":[[2020,6,10]],"date-time":"2020-06-10T22:15:32Z","timestamp":1591827332000},"page":"3170-3182","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":14,"title":["Hydroalkylation of Aryl Alkenes with Organohalides Catalyzed by Molybdenum Oxido Based Lewis Pairs"],"prefix":"10.1002","volume":"362","author":[{"given":"Niklas","family":"Zwettler","sequence":"first","affiliation":[{"name":"Institute of Chemistry University of Graz  Schubertstrasse 1 8010 Graz Austria"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Antoine","family":"Dup\u00e9","sequence":"additional","affiliation":[{"name":"Institute of Chemistry University of Graz  Schubertstrasse 1 8010 Graz Austria"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Sumea","family":"Kloki\u0107","sequence":"additional","affiliation":[{"name":"Institute of Chemistry University of Graz  Schubertstrasse 1 8010 Graz Austria"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Angela","family":"Milinkovi\u0107","sequence":"additional","affiliation":[{"name":"Institute of Chemistry University of Graz  Schubertstrasse 1 8010 Graz Austria"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Dado","family":"Rodi\u0107","sequence":"additional","affiliation":[{"name":"Institute of Chemistry University of Graz  Schubertstrasse 1 8010 Graz Austria"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Simon","family":"Walg","sequence":"additional","affiliation":[{"name":"Institute of Chemistry University of Graz  Schubertstrasse 1 8010 Graz Austria"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Dmytro","family":"Neshchadin","sequence":"additional","affiliation":[{"name":"Institute for Physical and Theoretical Chemistry Graz University of Technology  Stremayrgasse 9 8010 Graz Austria"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ferdinand","family":"Belaj","sequence":"additional","affiliation":[{"name":"Institute of Chemistry University of Graz  Schubertstrasse 1 8010 Graz Austria"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Nadia C.","family":"M\u00f6sch\u2010Zanetti","sequence":"additional","affiliation":[{"name":"Institute of Chemistry University of Graz  Schubertstrasse 1 8010 Graz Austria"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2020,6,29]]},"reference":[{"key":"e_1_2_6_2_1","unstructured":"\u00a0"},{"key":"e_1_2_6_3_2","doi-asserted-by":"publisher","DOI":"10.1039\/b819621d"},{"key":"e_1_2_6_4_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200903708"},{"key":"e_1_2_6_5_2","doi-asserted-by":"publisher","DOI":"10.1039\/b710475h"},{"key":"e_1_2_6_6_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.1134230"},{"key":"e_1_2_6_7_1","unstructured":"\u00a0"},{"key":"e_1_2_6_8_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201706226"},{"key":"e_1_2_6_9_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201711945"},{"key":"e_1_2_6_10_2","doi-asserted-by":"publisher","DOI":"10.1039\/C4SC00395K"},{"key":"e_1_2_6_11_2","first-page":"354","author":"Stephan D. 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