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Tertiary chiral alcohols are obtained with ee's up to 94% and two stereogenic centers can be created. Compared to the previous lactone reagent the stereopreference switches almost completely, proving the fact that the nature of the organometallic compound is of immense importance for the asymmetry of the product.<\/jats:p><jats:p><jats:boxed-text content-type=\"graphic\" position=\"anchor\"><jats:graphic xmlns:xlink=\"http:\/\/www.w3.org\/1999\/xlink\" mimetype=\"image\/png\" position=\"anchor\" specific-use=\"enlarged-web-image\" xlink:href=\"graphic\/adsc202100037-toc-0001-m.png\"><jats:alt-text>magnified image<\/jats:alt-text><\/jats:graphic><\/jats:boxed-text>\n<\/jats:p>","DOI":"10.1002\/adsc.202100037","type":"journal-article","created":{"date-parts":[[2021,4,6]],"date-time":"2021-04-06T22:05:50Z","timestamp":1617746750000},"page":"3138-3143","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":5,"title":["Asymmetric Allylation Catalyzed by Chiral Phosphoric Acids: Stereoselective Synthesis of Tertiary Alcohols and a Reagent\u2010Based Switch in Stereopreference"],"prefix":"10.1002","volume":"363","author":[{"given":"Mattia","family":"Lazzarotto","sequence":"first","affiliation":[{"name":"University of Graz Institute of Chemistry, Bioorganic and Organic Chemistry  Heinrichstrasse 28\/II 8010 Graz Austria"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Peter","family":"Hartmann","sequence":"additional","affiliation":[{"name":"University of Graz Institute of Chemistry, Bioorganic and Organic Chemistry  Heinrichstrasse 28\/II 8010 Graz Austria"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jakob","family":"Pletz","sequence":"additional","affiliation":[{"name":"University of Graz Institute of Chemistry, Bioorganic and Organic Chemistry  Heinrichstrasse 28\/II 8010 Graz Austria"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ferdinand","family":"Belaj","sequence":"additional","affiliation":[{"name":"University of Graz Institute of Chemistry Inorganic Chemistry  Schubertstra\u00dfe 1\/III 8010 Graz Austria"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2151-6394","authenticated-orcid":false,"given":"Wolfgang","family":"Kroutil","sequence":"additional","affiliation":[{"name":"University of Graz Institute of Chemistry, Bioorganic and Organic Chemistry  Heinrichstrasse 28\/II 8010 Graz Austria"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Stefan E.","family":"Payer","sequence":"additional","affiliation":[{"name":"University of Graz Institute of Chemistry, Bioorganic and Organic Chemistry  Heinrichstrasse 28\/II 8010 Graz Austria"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Michael","family":"Fuchs","sequence":"additional","affiliation":[{"name":"University of Graz Institute of Chemistry, Bioorganic and Organic Chemistry  Heinrichstrasse 28\/II 8010 Graz Austria"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2021,5,5]]},"reference":[{"key":"e_1_2_2_2_1","unstructured":"\u00a0"},{"key":"e_1_2_2_3_2","doi-asserted-by":"publisher","DOI":"10.1039\/b007664n"},{"key":"e_1_2_2_4_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.198500941"},{"key":"e_1_2_2_4_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.19850970206"},{"key":"e_1_2_2_5_2","doi-asserted-by":"publisher","DOI":"10.1002\/anie.200903108"},{"key":"e_1_2_2_5_3","doi-asserted-by":"publisher","DOI":"10.1002\/ange.200903108"},{"key":"e_1_2_2_6_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0040-4020(97)00199-3"},{"key":"e_1_2_2_7_2","doi-asserted-by":"publisher","DOI":"10.1021\/cr60230a002"},{"key":"e_1_2_2_8_2","doi-asserted-by":"publisher","DOI":"10.1016\/B978-0-12-800070-0.00010-4"},{"key":"e_1_2_2_9_1","doi-asserted-by":"publisher","DOI":"10.1021\/jo00350a061"},{"key":"e_1_2_2_10_1","doi-asserted-by":"publisher","DOI":"10.1021\/np9803777"},{"key":"e_1_2_2_11_1","unstructured":"\u00a0"},{"key":"e_1_2_2_12_2","doi-asserted-by":"publisher","DOI":"10.1016\/S0140-6736(97)01339-1"},{"key":"e_1_2_2_13_2","doi-asserted-by":"publisher","DOI":"10.1080\/01635581.2001.9680616"},{"key":"e_1_2_2_14_2","first-page":"869","volume":"1","author":"Saarinen N. 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