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Despite these recent reports, there still remains a need to increase the utility and practicality of these reactions by exploring new radical coupling partners. Herein, we report the synthesis of \u03b3\u2010aryloxyketones via combined NHC\/photoredox catalysis. In this reaction, an \u03b1\u2010aryloxymethyl radical is generated via oxidation of an aryloxymethyl potassium trifluoroborate salt, which is then added into styrene derivatives to provide a stabilized benzylic radical. Subsequent radical\u2010radical coupling reaction with an azolium radical affords the \u03b3\u2010aryloxy ketone products.<\/jats:p><jats:p><jats:boxed-text content-type=\"graphic\" position=\"anchor\"><jats:graphic xmlns:xlink=\"http:\/\/www.w3.org\/1999\/xlink\" mimetype=\"image\/png\" position=\"anchor\" specific-use=\"enlarged-web-image\" xlink:href=\"graphic\/adsc202101354-toc-0001-m.png\"><jats:alt-text>magnified image<\/jats:alt-text><\/jats:graphic><\/jats:boxed-text>\n<\/jats:p>","DOI":"10.1002\/adsc.202101354","type":"journal-article","created":{"date-parts":[[2021,12,1]],"date-time":"2021-12-01T22:23:53Z","timestamp":1638397433000},"page":"518-524","update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":44,"title":["Combined Photoredox and Carbene Catalysis for the Synthesis of \u03b3\u2010Aryloxy Ketones"],"prefix":"10.1002","volume":"364","author":[{"given":"Pengzhi","family":"Wang","sequence":"first","affiliation":[{"name":"Department of Chemistry Northwestern University  Silverman Hall Evanston Illinois 60208 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Keegan P.","family":"Fitzpatrick","sequence":"additional","affiliation":[{"name":"Department of Chemistry Northwestern University  Silverman Hall Evanston Illinois 60208 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4856-3569","authenticated-orcid":false,"given":"Karl A.","family":"Scheidt","sequence":"additional","affiliation":[{"name":"Department of Chemistry Northwestern University  Silverman Hall Evanston Illinois 60208 USA"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2021,12,13]]},"reference":[{"key":"e_1_2_2_2_1","unstructured":"\u00a0"},{"key":"e_1_2_2_3_2","doi-asserted-by":"publisher","DOI":"10.1039\/c2cs15333e"},{"key":"e_1_2_2_4_2","doi-asserted-by":"publisher","DOI":"10.1038\/nature13384"},{"key":"e_1_2_2_5_2","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.5b00060"},{"key":"e_1_2_2_6_2","doi-asserted-by":"publisher","DOI":"10.1038\/s41570-021-00321-1"},{"key":"e_1_2_2_7_1","unstructured":"\u00a0"},{"key":"e_1_2_2_8_2","doi-asserted-by":"publisher","DOI":"10.1248\/yakushi1881.63.6_296"},{"key":"e_1_2_2_9_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja01547a064"},{"key":"e_1_2_2_10_2","doi-asserted-by":"publisher","DOI":"10.1039\/D1SC01910D"},{"key":"e_1_2_2_11_1","unstructured":"\u00a0"},{"key":"e_1_2_2_12_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja5080739"},{"key":"e_1_2_2_13_2","doi-asserted-by":"publisher","DOI":"10.1021\/ja511371a"},{"key":"e_1_2_2_14_2","doi-asserted-by":"publisher","DOI":"10.1039\/D0SC01538E"},{"key":"e_1_2_2_15_2","doi-asserted-by":"publisher","DOI":"10.1039\/D0SC03595E"},{"key":"e_1_2_2_16_2","volume":"32","author":"Dai L.","year":"2020","journal-title":"Chin. 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