{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,27]],"date-time":"2026-09-27T07:53:56Z","timestamp":1790495636510,"version":"4.1.0"},"reference-count":47,"publisher":"Wiley","issue":"1","license":[{"start":{"date-parts":[[2016,9,8]],"date-time":"2016-09-08T00:00:00Z","timestamp":1473292800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100001691","name":"Japan Society for the Promotion of Science","doi-asserted-by":"publisher","award":["12J02558"],"award-info":[{"award-number":["12J02558"]}],"id":[{"id":"10.13039\/501100001691","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Advanced Science"],"published-print":{"date-parts":[[2017,1]]},"abstract":"<jats:p>Daylight\u2010driven photocatalysts have attracted much attention in the context of \u201cgreen\u201d technology. Although various active materials have been reported and their applications are rapidly increasing, many are discovered after enormous experimental efforts. Herein the discovery of a novel oxide photocatalyst, \u03b2\u2010SnMoO<jats:sub>4<\/jats:sub>, is demonstrated via a rational search of 3483 known and hypothetical compounds with various compositions and structures over the whole range of SnO\u2010<jats:italic>M<\/jats:italic>O<jats:italic><jats:sub>q<\/jats:sub><\/jats:italic><jats:sub>\/2<\/jats:sub> (<jats:italic>M<\/jats:italic>: Ti, Zr, and Hf (<jats:italic>q<\/jats:italic> = 4); V, Nb, and Ta (<jats:italic>q<\/jats:italic> = 5); Cr, Mo, and W (<jats:italic>q<\/jats:italic> = 6)) pseudobinary systems. Screening using thermodynamic stability, band gap, and band\u2010edge positions by density functional theory calculations identifies \u03b2\u2010SnMoO<jats:sub>4<\/jats:sub> as a potential target. Then a low temperature route is used to successfully synthesize the novel crystal, which is confirmed by X\u2010ray powder diffraction and M\u00f6ssbauer spectroscopy. \u03b2\u2010SnMoO<jats:sub>4<\/jats:sub> is active for the photocatalytic decomposition of a methylene blue solution under daylight and its activity is comparable to a known photocatalyst, \u03b2\u2010SnWO<jats:sub>4<\/jats:sub>.<\/jats:p>","DOI":"10.1002\/advs.201600246","type":"journal-article","created":{"date-parts":[[2016,9,8]],"date-time":"2016-09-08T11:11:00Z","timestamp":1473333060000},"source":"Crossref","is-referenced-by-count":25,"title":["Discovery of a Novel Sn(II)\u2010Based Oxide \u03b2\u2010SnMoO<sub>4<\/sub> for Daylight\u2010Driven Photocatalysis"],"prefix":"10.1002","volume":"4","author":[{"given":"Hiroyuki","family":"Hayashi","sequence":"first","affiliation":[{"name":"Department of Materials Science and Engineering Kyoto University  Sakyo Kyoto 606\u20108501 Japan"},{"name":"Center for Materials Research by Information Integration National Institute for Materials Science  Tsukuba 305\u20100047 Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shota","family":"Katayama","sequence":"additional","affiliation":[{"name":"Department of Materials Science and Engineering Kyoto University  Sakyo Kyoto 606\u20108501 Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Takahiro","family":"Komura","sequence":"additional","affiliation":[{"name":"Department of Materials Science and Engineering Kyoto University  Sakyo Kyoto 606\u20108501 Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yoyo","family":"Hinuma","sequence":"additional","affiliation":[{"name":"Department of Materials Science and Engineering Kyoto University  Sakyo Kyoto 606\u20108501 Japan"},{"name":"Center for Materials Research by Information Integration National Institute for Materials Science  Tsukuba 305\u20100047 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