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However, the intrinsic instability of FL\u2010BP greatly limits its practical application. In this study, the amphiphobic FL\u2010BP is achieved by functionalization of 1<jats:italic>H<\/jats:italic>,1<jats:italic>H<\/jats:italic>,2<jats:italic>H<\/jats:italic>,2<jats:italic>H<\/jats:italic>\u2010perfluorooctyltrichlorosilane (PFDTS) on the surface of FL\u2010BP. The obtained PFDTS coated FL\u2010BP (FL\u2010BP\/PFDTS) demonstrates enhanced stability, which is not observed during significant degradation for 2 months in high moisture content environment (95% humidity). Particularly, attributing to the surface amphiphobicity, FL\u2010BP\/PFDTS exhibits strong surface water repellency in the presence of oleic acid (as the contaminant), while other passivation coating layers (such as hydrophilic or hydrophobic coating) become hydrophilicity under such conditions. Owing to this advantage, the obtained FL\u2010BP\/PFDTS demonstrates enhanced stability in high moisture content environment for 2 months, even though the surface is contaminated by oil liquid or other organic solvents (such as oleic acid, CH<jats:sub>2<\/jats:sub>Cl<jats:sub>2<\/jats:sub>, and <jats:italic>N<\/jats:italic>\u2010methyl\u20102\u2010pyrrolidone). The passivation of FL\u2010BP by amphiphobic coating provides an effective approach for FL\u2010BP stabilization toward future applications.<\/jats:p>","DOI":"10.1002\/advs.201901991","type":"journal-article","created":{"date-parts":[[2019,10,1]],"date-time":"2019-10-01T00:02:40Z","timestamp":1569888160000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":52,"title":["Robust Amphiphobic Few\u2010Layer Black Phosphorus Nanosheet with Improved Stability"],"prefix":"10.1002","volume":"6","author":[{"given":"Xiao","family":"Liu","sequence":"first","affiliation":[{"name":"Department of Biomaterials College of Materials Xiamen University  Xiamen 361005 P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yunfei","family":"Bai","sequence":"additional","affiliation":[{"name":"Department of Biomaterials College of Materials Xiamen University  Xiamen 361005 P. R. 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