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Here, a strategy is reported to realize high\u2010performance sodium\u2010ion energy storage using battery\u2010type anode and capacitor\u2010type cathode materials. First, nitrogen\u2010doped mesoporous titanium dioxide (NMTiO<jats:sub>2<\/jats:sub>) structures are synthesized via the controlled pyrolysis of metal\u2013organic frameworks. They exhibit interconnected open mesopores allowing fast ion transport and robust cycle stability with nearly 100% coulombic efficiency, along with rich redox\u2010reactive sites allowing high capacity even at a high rate of \u224890 C. Moreover, assembling the NMTiO<jats:sub>2<\/jats:sub> anode with the nitrogen\u2010doped graphene (NG) cathode in an asymmetric full cell shows a high energy density exceeding its counterpart symmetric cell by more than threefold as well as robust cycle stability over 10 000 cycles. Additionally, it gives a high\u2010power density close to 26 000 W kg<jats:sup>\u22121<\/jats:sup> outperforming that of a conventional sodium\u2010ion battery by several hundred fold, so that full cells can be charged within a few tens of seconds by the flexible photovoltaic charging and universal serial bus charging modules.<\/jats:p>","DOI":"10.1002\/advs.201902986","type":"journal-article","created":{"date-parts":[[2020,1,27]],"date-time":"2020-01-27T05:08:38Z","timestamp":1580101718000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":19,"title":["Synthesis of Nitrogen\u2010Doped Mesoporous Structures from Metal\u2013Organic Frameworks and Their Utilization Enabling High Performances in Hybrid Sodium\u2010Ion Energy Storages"],"prefix":"10.1002","volume":"7","author":[{"given":"Gyu Heon","family":"Lee","sequence":"first","affiliation":[{"name":"Department of Materials Science and Engineering Korea Advanced Institute of Science and Technology (KAIST)  291 Daehak\u2010ro, Yuseong\u2010gu Daejeon 34141 Republic of Korea"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3409-7544","authenticated-orcid":false,"given":"Jeung Ku","family":"Kang","sequence":"additional","affiliation":[{"name":"Department of Materials Science and Engineering Korea Advanced Institute of Science and Technology (KAIST)  291 Daehak\u2010ro, Yuseong\u2010gu Daejeon 34141 Republic of Korea"},{"name":"Graduated School of Energy, Environment, Water, and Sustainability (EEWS) NanoCentury KAIST Institute Korea Advanced Institute of Science and Technology (KAIST)  291 Daehak\u2010ro, Yuseong\u2010gu Daejeon 34141 Republic of Korea"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2020,1,27]]},"reference":[{"key":"e_1_2_5_1_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.pnsc.2008.07.014"},{"key":"e_1_2_5_2_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.epsr.2008.09.017"},{"key":"e_1_2_5_3_1","doi-asserted-by":"publisher","DOI":"10.1109\/5.975900"},{"key":"e_1_2_5_4_1","doi-asserted-by":"publisher","DOI":"10.1039\/C4CS00266K"},{"key":"e_1_2_5_5_1","doi-asserted-by":"publisher","DOI":"10.1142\/9789814287005_0033"},{"key":"e_1_2_5_6_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.1158736"},{"key":"e_1_2_5_7_1","doi-asserted-by":"publisher","DOI":"10.1039\/C5CS00580A"},{"key":"e_1_2_5_8_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.8b00116"},{"key":"e_1_2_5_9_1","first-page":"578","volume":"2","author":"Gu H.","year":"2016","journal-title":"Chem. 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