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However, the therapeutic effect of catalytic therapy is seriously restricted by the fast charge recombination and the limited utilization of exogenous stimulation by catalysts. In the past few decades, many strategies have been developed to overcome the above serious drawbacks, among which heterojunctions are the most widely used and promising strategy. This review attempts to summarize the recent progress in the rational design and fabrication of heterojunction nanomedicine, such as semiconductor\u2013semiconductor heterojunctions (including type I, type II, type III, P\uf8ffN, and Z\u2013scheme junctions) and semiconductor\u2013metal heterojunctions (including Schottky, Ohmic, and localized surface plasmon resonance\u2013mediated junctions). The catalytic mechanisms and properties of the above junction systems are also discussed in relation to biomedical applications, especially cancer treatment and sterilization. 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